• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

丝胶茧生物相容剂用于热塑性木薯淀粉的反应性共混。

Sericin cocoon bio-compatibilizer for reactive blending of thermoplastic cassava starch.

机构信息

School of Agro-Industry, Faculty of Agro-Industry, Chiang Mai University, Mae Hia, Muang, Chiang Mai, Thailand.

Cluster of Agro Bio-Circular-Green Industry, Faculty of Agro-Industry, Chiang Mai University, Mae Hia, Muang, Chiang Mai, Thailand.

出版信息

Sci Rep. 2021 Oct 7;11(1):19945. doi: 10.1038/s41598-021-99417-3.

DOI:10.1038/s41598-021-99417-3
PMID:34620941
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8497493/
Abstract

Cassava starch was blended with glycerol to prepare thermoplastic starch (TPS). Thermoplastic starch was premixed with sericin (TPSS) by solution mixing and then melt-blended with polyethylene grafted maleic anhydride (PEMAH). The effect of sericin on the mechanical properties, morphology, thermal properties, rheology, and reaction mechanism was investigated. The tensile strength and elongation at break of the TPSS10/PEMAH blend were improved to 12.2 MPa and 100.4%, respectively. The TPS/PEMAH morphology presented polyethylene grafted maleic anhydride particles (2 μm) dispersed in the thermoplastic starch matrix, which decreased in size to approximately 200 nm when 5% sericin was used. The melting temperature of polyethylene grafted maleic anhydride (121 °C) decreased to 111 °C because of the small crystal size of the polyethylene grafted maleic anhydride phase. The viscosity of TPS/PEMAH increased with increasing sericin content because of the chain extension. Fourier-transform infrared spectroscopy confirmed the reaction between the amino groups of sericin and the maleic anhydride groups of polyethylene grafted maleic anhydride. This reaction reduced the interfacial tension between thermoplastic starch and polyethylene grafted maleic anhydride, which improved the compatibility, mechanical properties, and morphology of the blend.

摘要

木薯淀粉与甘油混合制备热塑性淀粉（TPS）。热塑性淀粉通过溶液混合与丝胶（TPSS）预混合，然后与接枝马来酸酐的聚乙烯（PEMAH）熔融共混。研究了丝胶对力学性能、形态、热性能、流变性能和反应机理的影响。TPSS10/PEMAH 共混物的拉伸强度和断裂伸长率分别提高到 12.2 MPa 和 100.4%。TPS/PEMAH 的形态呈现出接枝马来酸酐的聚乙烯颗粒（2 μm）分散在热塑性淀粉基体中，当使用 5%丝胶时，其尺寸减小至约 200 nm。由于接枝马来酸酐相的小晶体尺寸，接枝马来酸酐的聚乙烯的熔融温度（121°C）降低至 111°C。由于链延伸，TPS/PEMAH 的粘度随丝胶含量的增加而增加。傅里叶变换红外光谱证实了丝胶的氨基与接枝马来酸酐的聚乙烯的马来酸酐基团之间的反应。这种反应降低了热塑性淀粉和接枝马来酸酐的聚乙烯之间的界面张力，从而改善了共混物的相容性、力学性能和形态。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/d28f3b81ebbe/41598_2021_99417_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/665a1d045878/41598_2021_99417_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/4888960b4846/41598_2021_99417_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/b6325665f632/41598_2021_99417_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/69ba25d31b66/41598_2021_99417_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/4273789efaf5/41598_2021_99417_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/027f21c23941/41598_2021_99417_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/267821d62ebc/41598_2021_99417_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/d28f3b81ebbe/41598_2021_99417_Fig8_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/665a1d045878/41598_2021_99417_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/4888960b4846/41598_2021_99417_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/b6325665f632/41598_2021_99417_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/69ba25d31b66/41598_2021_99417_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/4273789efaf5/41598_2021_99417_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/027f21c23941/41598_2021_99417_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/267821d62ebc/41598_2021_99417_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/28e2/8497493/d28f3b81ebbe/41598_2021_99417_Fig8_HTML.jpg

相似文献

1
Sericin cocoon bio-compatibilizer for reactive blending of thermoplastic cassava starch.丝胶茧生物相容剂用于热塑性木薯淀粉的反应性共混。
Sci Rep. 2021 Oct 7;11(1):19945. doi: 10.1038/s41598-021-99417-3.
2
Thermoplastic cassava starch blend with polyethylene-grafted-maleic anhydride and gelatin core-shell structure compatibilizer.热塑性木薯淀粉与接枝马来酸酐的聚乙烯共混物和明胶核壳结构增容剂。
Int J Biol Macromol. 2022 Feb 1;197:49-54. doi: 10.1016/j.ijbiomac.2021.12.003. Epub 2021 Dec 16.
3
Reactive blending of thermoplastic starch and polyethylene-graft-maleic anhydride with chitosan as compatibilizer.热塑性淀粉与聚乙烯-接枝-马来酸酐与壳聚糖作为相容剂的反应共混。
Carbohydr Polym. 2016 Nov 20;153:89-95. doi: 10.1016/j.carbpol.2016.07.091. Epub 2016 Jul 22.
4
Mechanical properties improvement of thermoplastic corn starch and polyethylene-grafted-maleicanhydride blending by Na ions neutralization of carboxymethyl cellulose.通过羧甲基纤维素钠对马来酸酐接枝聚乙烯的中和作用提高热塑性玉米淀粉与聚乙烯共混物的力学性能。
Int J Biol Macromol. 2018 Dec;120(Pt A):297-301. doi: 10.1016/j.ijbiomac.2018.08.076. Epub 2018 Aug 18.
5
Study on ternary low density polyethylene/linear low density polyethylene/thermoplastic starch blend films.三元低密度聚乙烯/线性低密度聚乙烯/热塑性淀粉共混薄膜的研究。
Carbohydr Polym. 2015 Mar 30;119:126-33. doi: 10.1016/j.carbpol.2014.11.038. Epub 2014 Dec 3.
6
A new approach in compatibilization of the poly(lactic acid)/thermoplastic starch (PLA/TPS) blends.一种用于增容聚乳酸/热塑性淀粉（PLA/TPS）共混物的新方法。
Carbohydr Polym. 2016 Jun 25;144:254-62. doi: 10.1016/j.carbpol.2016.02.035. Epub 2016 Feb 23.
7
Reactive Blending of Modified Thermoplastic Starch Chlorhexidine Gluconate and Poly(butylene succinate) Blending with Epoxy Compatibilizer.改性热塑性淀粉葡萄糖酸氯己定与聚丁二酸丁二醇酯与环氧增容剂的反应共混
Polymers (Basel). 2023 Aug 21;15(16):3487. doi: 10.3390/polym15163487.
8
Effect of Dip Coating Polymer Solutions on Properties of Thermoplastic Cassava Starch.浸涂聚合物溶液对热塑性木薯淀粉性能的影响。
Polymers (Basel). 2019 Oct 24;11(11):1746. doi: 10.3390/polym11111746.
9
Thermoplastic mung bean starch/natural rubber/sericin blends for improved oil resistance.热塑性绿豆淀粉/天然橡胶/丝胶共混物，提高耐油性。
Int J Biol Macromol. 2021 Oct 1;188:283-289. doi: 10.1016/j.ijbiomac.2021.07.187. Epub 2021 Jul 31.
10
Super-tough poly (l-lactide) materials: Reactive blending with maleic anhydride grafted starch and poly (ethylene glycol) diacrylate.超韧聚（L-丙交酯）材料：马来酸酐接枝淀粉和聚乙二醇二丙烯酸酯的反应共混。
Int J Biol Macromol. 2019 Sep 1;136:1069-1075. doi: 10.1016/j.ijbiomac.2019.06.141. Epub 2019 Jun 20.

引用本文的文献

1
Sericin coats of silk fibres, a degumming waste or future material?丝纤维的丝胶涂层，是脱胶废料还是未来材料？
Mater Today Bio. 2024 Oct 24;29:101306. doi: 10.1016/j.mtbio.2024.101306. eCollection 2024 Dec.
2
Modified Poly(Lactic Acid) Epoxy Resin Using Chitosan for Reactive Blending with Epoxidized Natural Rubber: Analysis of Annealing Time.使用壳聚糖对聚乳酸环氧树脂进行改性以与环氧化天然橡胶进行反应共混：退火时间分析
Polymers (Basel). 2022 Mar 8;14(6):1085. doi: 10.3390/polym14061085.
3
Effect of Egg-Coating Material Properties by Blending Cassava Starch with Methyl Celluloses and Waxes on Egg Quality.

本文引用的文献

1
Morphological and mechanical properties of biodegradable poly(glycolic acid)/poly(butylene adipate--terephthalate) blends with compatibilization.具有增容作用的可生物降解聚乙醇酸/聚己二酸-对苯二甲酸丁二醇酯共混物的形态学和力学性能
RSC Adv. 2021 Jan 4;11(3):1241-1249. doi: 10.1039/d0ra08813g.
2
Characterization of Chitosan Film Incorporated with Curcumin Extract.含姜黄素提取物的壳聚糖膜的表征
Polymers (Basel). 2021 Mar 21;13(6):963. doi: 10.3390/polym13060963.
3
Effect of Monochloroacetic Acid on Properties of Carboxymethyl Bacterial Cellulose Powder and Film from Nata de Coco.
木薯淀粉与甲基纤维素及蜡混合对蛋涂层材料性能的影响及其对鸡蛋品质的作用
Polymers (Basel). 2021 Nov 1;13(21):3787. doi: 10.3390/polym13213787.
一氯乙酸对椰果羧甲基细菌纤维素粉末和薄膜性能的影响。
Polymers (Basel). 2021 Feb 4;13(4):488. doi: 10.3390/polym13040488.
4
Carboxymethyl Bacterial Cellulose from Nata de Coco: Effects of NaOH.来自椰果的羧甲基细菌纤维素：氢氧化钠的影响。
Polymers (Basel). 2021 Jan 22;13(3):348. doi: 10.3390/polym13030348.
5
Molecular Dynamics Simulations of Crystal Nucleation near Interfaces in Incompatible Polymer Blends.不相容聚合物共混物中界面附近晶体成核的分子动力学模拟
Polymers (Basel). 2021 Jan 22;13(3):347. doi: 10.3390/polym13030347.
6
Synthesis, Characterization, and Application of Carboxymethyl Cellulose from Asparagus Stalk End.芦笋茎末端羧甲基纤维素的合成、表征及应用
Polymers (Basel). 2020 Dec 28;13(1):81. doi: 10.3390/polym13010081.
7
Physical Properties of Carboxymethyl Cellulose from Palm Bunch and Bagasse Agricultural Wastes: Effect of Delignification with Hydrogen Peroxide.棕榈果串和甘蔗渣农业废弃物中羧甲基纤维素的物理性质：过氧化氢脱木质素的影响
Polymers (Basel). 2020 Jul 7;12(7):1505. doi: 10.3390/polym12071505.
8
Antioxidant and Moisturizing Properties of Carboxymethyl Chitosan with Different Molecular Weights.不同分子量羧甲基壳聚糖的抗氧化和保湿性能
Polymers (Basel). 2020 Jun 28;12(7):1445. doi: 10.3390/polym12071445.
9
Optimization of ultrasonic-assisted extraction of polysaccharides from purple glutinous rice bran (Oryza sativa L.) and their antioxidant activities.超声辅助提取紫糯米糠多糖及其抗氧化活性的优化。
Sci Rep. 2020 Jun 26;10(1):10410. doi: 10.1038/s41598-020-67266-1.
10
Effect of sodium benzoate and chlorhexidine gluconate on a bio-thermoplastic elastomer made from thermoplastic starch-chitosan blended with epoxidized natural rubber.苯甲酸钠和葡萄糖酸氯己定对热塑性淀粉-壳聚糖与环氧化天然橡胶共混的生物热塑性弹性体的影响。
Carbohydr Polym. 2020 Aug 15;242:116421. doi: 10.1016/j.carbpol.2020.116421. Epub 2020 May 12.