Alorabi Ali Q, Hassan M Shamshi, Algethami Jari S, Baghdadi Neazar Essam
Chemistry Department, Faculty of Science, 158203Albaha University, Albaha, Saudi Arabia.
Empty Quarter Research Unit, Chemistry Department, Faculty of Science and Arts at Sharurah, 158216Najran University, Najran, Sharurah, Saudi Arabia.
Sci Prog. 2021 Oct;104(4):368504211050300. doi: 10.1177/00368504211050300.
Heterostructure Ag-AgVO/CuO photocatalyst was prepared by the hydrothermal procedure. The prepared photocatalysts were characterized by different physico-chemical techniques. For Ag-AgVO/CuO composites, AgVO shows the monoclinic phase whereas Ag and CuO show a cubic phase. SEM images of Ag-AgVO/CuO composites illustrated that the surface of AgVO nanorods was covered by Ag and CuO nanoparticles. Ultra violet - visible diffuse reflectance spectra revealed that the calculated optical response of Ag-AgVO/CuO composite was found to be 2.24 eV. Additionally, the composite catalyst demonstrated improved photo-efficiency for the decolorization of methylene blue dye compared to that of pristine AgVO. The better performance of the composite sample can be ascribed to its high charge separation and inhibition in recombination of charges in Ag-AgVO/CuO catalyst Finally, this heterostructure Ag-AgVO/CuO catalyst demonstrated good stability which simply can be recycled a number of times with steadiness; thus, unwraps new possibilities for applications as innovative photocatalyst.
通过水热法制备了异质结构的Ag-AgVO/CuO光催化剂。采用不同的物理化学技术对制备的光催化剂进行了表征。对于Ag-AgVO/CuO复合材料,AgVO呈现单斜相,而Ag和CuO呈现立方相。Ag-AgVO/CuO复合材料的扫描电子显微镜图像表明,AgVO纳米棒的表面被Ag和CuO纳米颗粒覆盖。紫外可见漫反射光谱显示,计算得出Ag-AgVO/CuO复合材料的光学响应为2.24 eV。此外,与原始AgVO相比,复合催化剂对亚甲基蓝染料的脱色表现出更高的光效率。复合样品的更好性能可归因于其在Ag-AgVO/CuO催化剂中具有较高的电荷分离和抑制电荷复合的能力。最后,这种异质结构的Ag-AgVO/CuO催化剂表现出良好的稳定性,可简单地稳定循环使用多次;因此,为作为创新光催化剂的应用开辟了新的可能性。