Sun Xiaoguang, Cui Huaiyun, Li Zhong, He Renyang, Liu Zhiyong, Lu Lin
Institute for Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China.
CRRC Qingdao Sifang Co., Ltd., Qingdao 266111, China.
Materials (Basel). 2021 Sep 25;14(19):5575. doi: 10.3390/ma14195575.
The corrosion behavior of L80 casing steel was studied in a simulating annulus environment using the electrochemical measurement method, immersion test, and tensile test under a high-temperature and high-pressure HS/CO environment. The partial pressure of CO (PCO2), the partial pressure of HS (PH2S), water content, and preloading stress remarkably affected the corrosion behavior of L80 steel. The influence of PCO2 on stress corrosion cracking (SCC) susceptibility has an inflection point of approximately 1.1 MPa. The SCC susceptibility reaches the maximum when the PCO2 is about 1.1 MPa. The SCC susceptibility has a positive correlation to PH2S and water content. The higher water content of the corrosion medium can increase the electrical conductivity of the corrosion medium and promote the corrosion of L80 steel, which can improve the diffusion of hydrogen into steel and promote the SCC of L80 steel. Preloading stress can promote local corrosion, thereby promoting SCC of steel under stress. The dislocation emergence point caused by preloading stress can accelerate the diffusion of hydrogen into steel and increase SCC susceptibility.
采用电化学测量法、浸泡试验和拉伸试验,在高温高压HS/CO环境下的模拟环空环境中研究了L80套管钢的腐蚀行为。CO的分压(PCO2)、HS的分压(PH2S)、含水量和预加载应力对L80钢的腐蚀行为有显著影响。PCO2对应力腐蚀开裂(SCC)敏感性的影响有一个约1.1MPa的拐点。当PCO2约为1.1MPa时,SCC敏感性达到最大值。SCC敏感性与PH2S和含水量呈正相关。腐蚀介质中较高的含水量会增加腐蚀介质的电导率,促进L80钢的腐蚀,这会促进氢向钢中的扩散并促进L80钢的SCC。预加载应力会促进局部腐蚀,从而促进钢在应力作用下的SCC。由预加载应力引起的位错出现点会加速氢向钢中的扩散并增加SCC敏感性。