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用于建筑的地质聚合物中铅矿尾矿污染物元素的保留

Retention of Pollutants Elements from Mine Tailings of Lead in Geopolymers for Construction.

作者信息

Terrones-Saeta Juan María, Suárez-Macías Jorge, Castañón Ana María, Gómez-Fernández Fernando, Corpas-Iglesias Francisco Antonio

机构信息

Research Group TEP 222 "Materials and Mining Engineering", Higher Polytechnic School of Linares, University of Jaen, 23700 Linares, Spain.

Department of Mining, Topography and Structures, University of León (ESTIM), Campus de Vegazana, s.n, 24071 León, Spain.

出版信息

Materials (Basel). 2021 Oct 18;14(20):6184. doi: 10.3390/ma14206184.

Abstract

The construction sector is one of the most demanding sectors of raw materials in existence today. As a consequence, the extraction of these materials has a significant impact on the environment. At the same time, mining activities produce a series of wastes, in some cases with polluting elements, which must be treated to avoid pollution. Therefore, the use of mining waste for the conformation of new construction materials is an important environmental advantage, even more so when such waste is prevented from producing polluting leachates. Therefore, in this research, geopolymers are developed with mine tailings from the Linares lead mines, chemically activated with potassium hydroxide. For this purpose, different percentages of the alkaline activator were tested and the physical and mechanical properties of the conformed materials were evaluated. The analysis of the different conformed geopolymers determined the optimum percentage of potassium hydroxide for conforming the geopolymer with the best mechanical and physical properties. In addition, the concentration in the leachate of potentially contaminating chemical elements in the mining waste was estimated to be lower than those regulated by the regulations. Consequently, this research shows the development of a sustainable material for construction with mining waste and reduction of the environmental impact of traditional products.

摘要

建筑行业是当今对原材料需求最大的行业之一。因此,这些材料的开采对环境有重大影响。同时,采矿活动会产生一系列废物,在某些情况下还含有污染性元素,必须对其进行处理以避免污染。因此,将采矿废料用于新型建筑材料的制备具有重要的环境优势,尤其是当这种废料能够防止产生污染性渗滤液时。因此,在本研究中,利用来自利纳雷斯铅矿的尾矿开发了地质聚合物,并使用氢氧化钾进行化学活化。为此,测试了不同百分比的碱性活化剂,并评估了所制备材料的物理和力学性能。对不同制备的地质聚合物进行分析后,确定了制备具有最佳力学和物理性能的地质聚合物时氢氧化钾的最佳百分比。此外,估计采矿废料中潜在污染化学元素在渗滤液中的浓度低于法规规定的浓度。因此,本研究展示了一种利用采矿废料开发可持续建筑材料以及减少传统产品对环境影响的方法。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1a35/8540991/6f304b279de1/materials-14-06184-g001.jpg

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