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分子内运动受限(RIM)的机制内涵

Mechanistic connotations of restriction of intramolecular motions (RIM).

作者信息

Tu Yujie, Zhao Zheng, Lam Jacky W Y, Tang Ben Zhong

机构信息

Department of Chemistry, Hong Kong Branch of Chinese National Engineering Research Center for Tissue Restoration and Reconstruction, Institute for Advanced Study and Department of Chemical and Biological Engineering, The Hong Kong University of Science and Technology, China.

出版信息

Natl Sci Rev. 2021 Jun 11;8(6):nwaa260. doi: 10.1093/nsr/nwaa260. eCollection 2021 Jun.

DOI:10.1093/nsr/nwaa260
PMID:34691663
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8288185/
Abstract

Restriction of intramolecular motion (RIM) is the widely-accpeted mechanism of aggregation-induced emission (AIE). In this concise and comprehensive perspective, four mechanistic models related to different nonradiative pathways are summarized with examples to disclose the connotation of RIM, and meaningful mechanistic topics for future researches are advised.

摘要

分子内运动受限(RIM)是聚集诱导发光(AIE)被广泛接受的机制。在这篇简洁而全面的综述中,总结了与不同非辐射途径相关的四种机制模型,并举例揭示了RIM的内涵,同时提出了未来研究中有意义的机制性课题。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a257/8288185/a51703047d83/nwaa260fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a257/8288185/67c653594073/nwaa260fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a257/8288185/a51703047d83/nwaa260fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a257/8288185/67c653594073/nwaa260fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a257/8288185/a51703047d83/nwaa260fig2.jpg

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Aggregate Science: From Structures to Properties.凝聚态科学:从结构到性质
Adv Mater. 2020 Sep;32(36):e2001457. doi: 10.1002/adma.202001457. Epub 2020 Jul 30.
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Snooping on the conical intersection.窥探锥形交叉点。
Nat Rev Chem. 2025 Apr;9(4):206-207. doi: 10.1038/s41570-025-00699-2.
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