Amin Peshawa O, Muhammadsharif Fahmi F, Saeed Salah Raza, Sulaiman Khaulah
Charmo Center for Research, Training and Consultancy, Charmo University, 46023, Chamchamal, Kurdistan Region-F.R., Iraq.
Department of Physics, Faculty of Science and Health, Koya University, KOY45, Koya, Kurdistan Region-F.R., Iraq.
J Fluoresc. 2022 Jan;32(1):203-213. doi: 10.1007/s10895-021-02837-7. Epub 2021 Oct 25.
In this work, the optoelectronic parameters of natural dyes extracted from beetroot, red cabbage, walnut leaves, and henna were comprehensively investigated, namely the optical energy gap (E), extinction coefficient (k), refractive index (n), dielectric constant ([Formula: see text], and optical conductivity ([Formula: see text]. Results showed a high refractive index, dielectric constant and optical conductivity ([Formula: see text] and [Formula: see text]) for the dye extracted from red cabbage, while minimum values of [Formula: see text] and [Formula: see text] were obtained for the henna dye. The transition type of the optical absorption of the dyes was found to be a direct allowed transition, which is taken place between the bonding and antibonding molecular energy levels. The reported results herein are essential in revealing the viability of these natural dyes for potential applications in organic electronics, including organic photovoltaics, photodiodes, and sensors.
在这项工作中,对从甜菜根、红甘蓝、核桃叶和指甲花中提取的天然染料的光电参数进行了全面研究,即光学能隙(E)、消光系数(k)、折射率(n)、介电常数([公式:见正文])和光导率([公式:见正文])。结果表明,从红甘蓝中提取的染料具有较高的折射率、介电常数和光导率([公式:见正文]和[公式:见正文]),而指甲花染料的[公式:见正文]和[公式:见正文]值最小。发现这些染料的光吸收跃迁类型为直接允许跃迁,发生在成键和反键分子能级之间。本文报道的结果对于揭示这些天然染料在有机电子学潜在应用中的可行性至关重要,这些应用包括有机光伏、光电二极管和传感器。