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非木材废料来源的微纳米纤维素:工艺及在工业应用中的用途。

Micro- and nanocelluloses from non-wood waste sources; processes and use in industrial applications.

机构信息

Department of Chemistry and Materials Science, Aalto University, P.O. Box 16100, FI-00076 AALTO, Finland.

Kaisa Karisalmi, Kemira Oyj, Espoo R&D Center, Luoteisrinne 2, FI-02270 Espoo, Finland.

出版信息

Soft Matter. 2021 Nov 10;17(43):9842-9858. doi: 10.1039/d1sm00958c.

Abstract

In addition to renewability and abundance, nanocellulose materials have tremendous (and variable) properties for different applications, ranging from bulk applications, such as paper and packaging reinforcement, to emerging high added-value applications, such as substrates for optoelectronics. Lignocellulosic biomass from agricultural and industrial waste sources is readily available and shows great promise as an inexpensive and sustainable raw material for nanocellulose production. However, the understanding of the potential of using non-wood based biowaste sources is not established and systematic comparisons of versatile agricultural and industrial waste sources can elucidate this complex topic. Here we present an overview of the most studied and most promising sources from agro-industrial waste, the processes to convert them into nanocellulose, some of the established and emerging applications, and discuss the advancements that are still needed for large-scale production. Sugarcane bagasse and oil palm empty fruit bunch have been the most researched waste-based sources for nanocellulose production and demonstrate the most promise due to availability and access. Industrial sources seem to have advantages over agricultural sources in collectability and ease of access. This work gives insight on the potential and the challenges of nanocellulose production from waste sources and discusses how the criteria set for nanocellulose materials in different applications can be met, thus opening new routes for circular economy.

摘要

除了可再生性和丰富性外,纳米纤维素材料还具有巨大的(且可变的)特性,适用于从大规模应用(如纸张和包装增强)到新兴高附加值应用(如光电基板)等不同的应用。来自农业和工业废物来源的木质纤维素生物质很容易获得,并有望成为生产纳米纤维素的廉价且可持续的原料。然而,对于利用非木材基生物废物来源的潜力的理解尚未确定,并且对多功能农业和工业废物来源的系统比较可以阐明这一复杂主题。在这里,我们概述了来自农业-工业废物的最受研究和最有前途的来源、将它们转化为纳米纤维素的过程、一些已建立和新兴的应用,并讨论了大规模生产仍需要的进展。甘蔗渣和油棕空果串是研究最多的基于废物的纳米纤维素生产来源,由于可用性和获取性,它们显示出最大的潜力。工业来源在可收集性和易于获取性方面似乎优于农业来源。这项工作深入了解了从废物中生产纳米纤维素的潜力和挑战,并讨论了如何满足不同应用中纳米纤维素材料的标准,从而为循环经济开辟了新途径。

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