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废纸:未充分利用但有前途的纳米纤维素开采资源。

Waste paper: An underutilized but promising source for nanocellulose mining.

机构信息

Nanotechnology and Advanced Biomaterials Group, Avantha Centre for Industrial Research & Development, Paper Mill Campus, Yamuna Nagar 135001, India.

Avantha Centre for Industrial Research & Development, Paper Mill Campus, Yamuna Nagar 135001, India.

出版信息

Waste Manag. 2020 Feb 1;102:281-303. doi: 10.1016/j.wasman.2019.10.041. Epub 2019 Nov 5.

Abstract

Nanocellulose has achieved an inimitable place and value in nano-materials research sector. Promising and exclusive physical, chemical and biological properties of nanocellulose make it an attractive and ideal material for various high end-user applications. Conventionally, the base material for nanocellulose i.e. cellulose is being extracted from various lignocellulosic raw materials (like wood, agro-industrial-residues, etc.) using pulping followed by bleaching sequences. As an alternate to lignocellulosic raw materials, waste paper also showed potential as a competent raw material due to its abundant availability and high cellulosic content (60-70%) with comparatively less hemicelluloses (10-20%) and lignin (5-10%) without any harsh treatments. The production yields of nanocellulose were reported to vary from 1.5% to 64% depending upon the waste papers and treatments given. The diameters of these nanocelluloses were reported in the range of 2-100 nm and crystallinity range around 54-95%. Thermal degradation of waste paper nanocellulose was varied from 187 °C to 371 °C. Although these properties are comparable with the nanocellulose obtained from lignocellulosic raw materials, yet waste paper is an underutilized source for nanocellulose preparation due to its ordinary fate of recycling, dumping and incineration. In the sight of necessity and possibility of waste paper utilization, this article reviews the outcomes of research carried out for preparation of nanocellulose using waste paper as a source of cellulose. There is a need of sincere investigation to convert this valuable waste to wealth i.e. waste papers to nanocellulose, which will be helpful in solid waste management to protect environment in economical way.

摘要

纳米纤维素在纳米材料研究领域中占据着独特的地位和价值。纳米纤维素具有出色且独特的物理、化学和生物特性,使其成为各种高端应用的极具吸引力和理想的材料。传统上,纳米纤维素的基础材料即纤维素是通过制浆后再进行漂白等一系列工序从各种木质纤维素原料(如木材、农业工业废料等)中提取出来的。作为木质纤维素原料的替代品,废纸由于其丰富的可用性和较高的纤维素含量(60-70%)、相对较少的半纤维素(10-20%)和木质素(5-10%),而且无需进行任何苛刻的处理,也显示出作为一种有潜力的原料的可能性。纳米纤维素的产量据报道在 1.5%到 64%之间不等,具体取决于所使用的废纸种类和处理方式。这些纳米纤维素的直径报告在 2-100nm 范围内,结晶度在 54-95%左右。废纸纳米纤维素的热降解温度在 187°C 到 371°C 之间变化。虽然这些性能与从木质纤维素原料中获得的纳米纤维素相当,但由于废纸通常被回收、倾倒和焚烧,因此它仍然是一种未被充分利用的纳米纤维素制备原料。鉴于废纸利用的必要性和可能性,本文综述了以废纸为纤维素来源制备纳米纤维素的研究成果。有必要进行认真的研究,将这种有价值的废物转化为财富,即将废纸转化为纳米纤维素,这将有助于以经济的方式进行固体废物管理,保护环境。

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