Zheng Shuang, Tang Jiayue, Lv Dong, Wang Mi, Yang Xuan, Hou Changshun, Yi Bo, Lu Gang, Hao Ruiran, Wang Mingzhan, Wang Yanlei, He Hongyan, Yao Xi
Department of Biomedical Sciences, City University of Hong Kong, Hong Kong, China.
Department of Chemistry, Hong Kong University of Science and Technology, Hong Kong, China.
Adv Mater. 2022 Jan;34(4):e2106410. doi: 10.1002/adma.202106410. Epub 2021 Dec 6.
Humidity-based power generation that converts internal energy of water molecules into electricity is an emerging approach for harvesting clean energy from nature. Here it is proposed that intrinsic gradient within a humidity field near sweating surfaces, such as rivers, soil, or animal skin, is a promising power resource when integrated with liquid-infused nanofluidics. Specifically, capillary-stabilized ionic liquid (IL, Omim Cl ) film is exposed to the above humidity field to create a sustained transmembrane water-content difference, which enables asymmetric ion-diffusion across the nanoconfined fluidics, facilitating long-term electricity generation with the power density of ≈12.11 µW cm . This high record is attributed to the nanoconfined IL that integrates van der Waals and electrostatic interactions to block movement of Omim clusters while allowing for directional diffusion of moisture-liberated Cl . This humidity gradient triggers large ion-diffusion flux for power generation indicates great potential of sweating surfaces considering that most of the earth is covered by water or soil.
基于湿度的发电方式,即将水分子的内能转化为电能,是一种从自然界获取清洁能源的新兴方法。本文提出,在河流、土壤或动物皮肤等出汗表面附近的湿度场中,当与注入液体的纳米流体相结合时,其固有的梯度是一种很有前景的能源。具体而言,将毛细管稳定的离子液体(IL,氯化1-辛基-3-甲基咪唑鎓)薄膜暴露于上述湿度场中,以产生持续的跨膜含水量差异,这使得离子能够在纳米受限流体中不对称扩散,从而实现长期发电,功率密度约为12.11 μW/cm²。这一高纪录归因于纳米受限离子液体,它整合了范德华力和静电相互作用,阻止了氯化1-辛基-3-甲基咪唑鎓簇的移动,同时允许释放水分的氯离子定向扩散。这种湿度梯度触发了用于发电的大离子扩散通量,考虑到地球大部分地区被水或土壤覆盖,这表明出汗表面具有巨大的潜力。