Department of Chemistry, Indian Institute of Science Education and Research (IISER) Pune, Dr Homi Bhabha Road, Pashan, Pune 411008, India.
Department of Chemistry, Technical University of Munich, Lichtenbergstraße 4, 85748 Garching bei München, Germany.
Dalton Trans. 2021 Dec 14;50(48):17832-17850. doi: 10.1039/d1dt02862f.
Thanks to a bottom-up design of metals and organic ligands, the library of metal-organic frameworks (MOFs) has seen a conspicuous growth. Post-synthetically modified MOFs comprise a relatively smaller subset of this library. Whereas the approach of post-synthetic modification was seminally introduced for MOFs in the early 1990s, the earliest examples of post-synthetically modified MOFs are only congruous with adsorption and catalysis. The utility of PSM-derived MOFs for the sensing and capture of water contaminants is relatively niche. Arguably though, an increasing number of post-synthetically modified MOFs are finding relevance in the context of water pollutant remediation. In this article, we review the recent advances in this area and propose a structure-function relationship-guided blueprint for the future outlook.
由于金属和有机配体的自下而上设计，金属有机骨架（MOF）库已经显著增长。后合成修饰的 MOF 构成了这个库中相对较小的一部分。虽然后合成修饰的方法在 20 世纪 90 年代初就被引入到 MOF 中，但最早的后合成修饰的 MOF 仅与吸附和催化有关。PSM 衍生的 MOF 用于水污染物检测和捕获的应用相对较少。然而，可以说，越来越多的后合成修饰的 MOF 在水污染修复方面具有相关性。在本文中，我们综述了这一领域的最新进展，并提出了一个基于结构-功能关系的未来展望蓝图。
