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通过热机械纳米成型实现纳米制造

Unleashing nanofabrication through thermomechanical nanomolding.

作者信息

Liu Naijia, Liu Guannan, Raj Arindam, Sohn Sungwoo, Morales-Acosta Mayra Daniela, Liu Jingbei, Schroers Jan

机构信息

Department of Mechanical Engineering and Materials Science, Yale University, New Haven, CT 06511, USA.

Institute of Materials Science, University of Connecticut, Storrs, CT 06269, USA.

出版信息

Sci Adv. 2021 Nov 19;7(47):eabi4567. doi: 10.1126/sciadv.abi4567.

Abstract

Advancements in nanotechnology require the development of nanofabrication methods for a wide range of materials, length scales, and elemental distributions. Today’s nanofabrication methods are typically missing at least one demanded characteristic. Hence, a general method enabling versatile nanofabrication remains elusive. Here, we show that, when revealing and using the underlying mechanisms of thermomechanical nanomolding, a highly versatile nanofabrication toolbox is the result. Specifically, we reveal interface diffusion and dislocation slip as the controlling mechanisms and use their transition to control, combine, and predict the ability to fabricate general materials, material combinations, and length scales. Designing specific elemental distributions is based on the relative diffusivities, the transition temperature, and the distribution of the materials in the feedstock. The mechanistic origins of thermomechanical nanomolding and their homologous temperature-dependent transition suggest a versatile toolbox capable of combining many materials in nanostructures and potentially producing any material in moldable shapes on the nanoscale.

摘要

纳米技术的进步需要开发适用于多种材料、长度尺度和元素分布的纳米制造方法。当今的纳米制造方法通常至少缺少一种所需特性。因此,一种能够实现通用纳米制造的通用方法仍然难以捉摸。在这里,我们表明,当揭示并利用热机械纳米成型的潜在机制时,就会产生一个高度通用的纳米制造工具箱。具体而言,我们揭示了界面扩散和位错滑移作为控制机制,并利用它们的转变来控制、组合和预测制造通用材料、材料组合和长度尺度的能力。设计特定的元素分布基于相对扩散率、转变温度以及原料中材料的分布。热机械纳米成型的机理起源及其与温度相关的同源转变表明,存在一个通用的工具箱,能够在纳米结构中组合多种材料,并有可能在纳米尺度上制造出任何可成型形状的材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4502/8604398/5cdcc030e9e7/sciadv.abi4567-f1.jpg

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