Pan Yu, Le Congcong, He Bin, Watzman Sarah J, Yao Mengyu, Gooth Johannes, Heremans Joseph P, Sun Yan, Felser Claudia
Max Planck Institute for Chemical Physics of Solids, Dresden, Germany.
Department of Mechanical and Aerospace Engineering, The Ohio State University, Columbus, OH, USA.
Nat Mater. 2022 Feb;21(2):203-209. doi: 10.1038/s41563-021-01149-2. Epub 2021 Nov 22.
A large anomalous Nernst effect (ANE) is crucial for thermoelectric energy conversion applications because the associated unique transverse geometry facilitates module fabrication. Topological ferromagnets with large Berry curvatures show large ANEs; however, they face drawbacks such as strong magnetic disturbances and low mobility due to high magnetization. Herein, we demonstrate that YbMnBi, a canted antiferromagnet, has a large ANE conductivity of ~10 A m K that surpasses large values observed in other ferromagnets (3-5 A m K). The canted spin structure of Mn guarantees a non-zero Berry curvature, but generates only a weak magnetization three orders of magnitude lower than that of general ferromagnets. The heavy Bi with a large spin-orbit coupling enables a large ANE and low thermal conductivity, whereas its highly dispersive p orbitals ensure low resistivity. The high anomalous transverse thermoelectric performance and extremely small magnetization make YbMnBi an excellent candidate for transverse thermoelectrics.
大反常能斯特效应(ANE)对于热电能量转换应用至关重要,因为相关的独特横向几何结构便于模块制造。具有大贝里曲率的拓扑铁磁体表现出大的ANE;然而,它们面临诸如强磁干扰和由于高磁化导致的低迁移率等缺点。在此,我们证明了倾斜反铁磁体YbMnBi具有约10 A m K的大ANE电导率,超过了在其他铁磁体中观察到的大值(3 - 5 A m K)。Mn的倾斜自旋结构保证了非零的贝里曲率,但仅产生比一般铁磁体低三个数量级的弱磁化。具有大自旋 - 轨道耦合的重Bi元素能够实现大的ANE和低的热导率,而其高度色散的p轨道确保了低电阻率。高反常横向热电性能和极小的磁化使得YbMnBi成为横向热电学的极佳候选材料。