Kukhta Nadzeya A, Bryce Martin R
Department of Chemistry, Durham University, Lower Mountjoy, Stockton Road, Durham, DH1 3LE, UK.
Mater Horiz. 2021 Jan 1;8(1):33-55. doi: 10.1039/d0mh01316a. Epub 2020 Sep 21.
Purely organic molecules, which emit light by dual emissive (DE) pathways, have received increased attention in the last decade. These materials are now being utilized in practical optoelectronic, sensing and biomedical applications. In order to further extend the application of the DE emitters, it is crucial to gain a fundamental understanding of the links between the molecular structure and the underlying photophysical processes. This review categorizes the types of DE according to the spin multiplicity and time range of the emission, with emphasis on recent experimental advances. The design rules towards novel DE molecular candidates, the most perspective types of DE and possible future applications are outlined. These exciting developments highlight the opportunities for new materials synthesis and pave the way for accelerated future innovation and developments in this area.
在过去十年中,通过双发射(DE)途径发光的纯有机分子受到了越来越多的关注。这些材料目前正被用于实际的光电子、传感和生物医学应用中。为了进一步扩展DE发光体的应用,深入了解分子结构与潜在光物理过程之间的联系至关重要。本综述根据发射的自旋多重性和时间范围对DE类型进行了分类,重点介绍了最近的实验进展。概述了新型DE分子候选物的设计规则、最具前景的DE类型以及可能的未来应用。这些令人兴奋的进展突出了新材料合成的机遇,并为该领域未来的加速创新和发展铺平了道路。