Environmental Engineering Group, CSIR-Central Mechanical Engineering Research Institute, Durgapur, 713209, India.
Environmental Engineering Group, CSIR-Central Mechanical Engineering Research Institute, Durgapur, 713209, India.
J Environ Manage. 2022 Feb 1;303:114081. doi: 10.1016/j.jenvman.2021.114081. Epub 2021 Nov 22.
Groundwater contaminated with nitrate has prompted a flurry of research studies around the world in the recent years to address this burning environmental issue. The common presence of nitrates in groundwater, wastewater, and surface waters has thrown an enormously critical challenge to the global research communities to provide safe and clean drinking water to municipalities. As per WHO, the maximum permissible limit of nitrate in drinking water is 10 mg/L and in groundwater is 50 mg/L; exceeding the limits, several human health problems are observed. Adsorption, ion-exchange processes, membrane-based approaches, electrochemical and chemical procedures, biological methods, filtration, nanoparticles, etc. have been well investigated and reviewed to reduce nitrate levels in water samples in the recent years. Process conditions, as well as the efficacy of various approaches, were discovered to influence different techniques for nitrate mitigation. But, because of low cost, simple operation, easy handling, and high removal effectiveness, adsorption has been found to be the most suitable and efficient approach. The main objectives of this review primarily focuses on the creation of a naturally abundant, cost-effective innovative abundant material, such as activated clay particles combined with iron oxide. Oxide-clay nanocomposite materials, effectively remove nitrate with higher removal efficiency along with recovery of nitrate concentrated sludge. Such methods stand out as flexible and economic ways for capturing stabilized nitrate in solid matrices to satisfy long-term operations. A techno-economic assessment along with suitable policy suggestions have been reported to justify the viability of the brighter processes. Indeed, this kind of analytical review appears ideal for municipal community recommendations on abatement of excess nitrate to supply of clean water.
近年来,地下水受硝酸盐污染的问题引起了全球范围内的大量研究。由于硝酸盐普遍存在于地下水、废水和地表水,这给全球研究界带来了一个巨大的挑战,需要为市政当局提供安全清洁的饮用水。世界卫生组织规定,饮用水中硝酸盐的最大允许限量为 10mg/L,地下水中为 50mg/L;超过这些限制,就会出现一些人类健康问题。近年来,吸附、离子交换过程、基于膜的方法、电化学和化学程序、生物方法、过滤、纳米颗粒等已被广泛研究和综述,以降低水样中的硝酸盐含量。研究发现,处理条件以及各种方法的效果会影响不同的硝酸盐去除技术。但是,由于成本低、操作简单、易于处理且去除效率高,吸附被认为是最适合和有效的方法。本综述的主要目的是开发一种天然丰富、具有成本效益的创新丰富材料,例如与氧化铁结合的活性粘土颗粒。氧化物-粘土纳米复合材料可以有效地去除硝酸盐,具有更高的去除效率,并可以回收浓缩的硝酸盐污泥。这些方法作为一种灵活且经济的方式,用于将稳定的硝酸盐捕获在固体基质中,以满足长期运行的需求。已报告技术经济评估和适当的政策建议,以证明更优工艺的可行性。事实上,这种分析性综述非常适合市政社区提出的关于减少过量硝酸盐以供应清洁水的建议。