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一种用于中红外气体传感的高度稳定、纳米管增强的CMOS-MEMS热发射器。

A highly stable, nanotube-enhanced, CMOS-MEMS thermal emitter for mid-IR gas sensing.

作者信息

Popa Daniel, Hopper Richard, Ali Syed Zeeshan, Cole Matthew Thomas, Fan Ye, Veigang-Radulescu Vlad-Petru, Chikkaraddy Rohit, Nallala Jayakrupakar, Xing Yuxin, Alexander-Webber Jack, Hofmann Stephan, De Luca Andrea, Gardner Julian William, Udrea Florin

机构信息

Department of Engineering, University of Cambridge, Cambridge, CB3 0FA, UK.

Flusso Limited, Cambridge, CB4 0DL, UK.

出版信息

Sci Rep. 2021 Nov 25;11(1):22915. doi: 10.1038/s41598-021-02121-5.

Abstract

The gas sensor market is growing fast, driven by many socioeconomic and industrial factors. Mid-infrared (MIR) gas sensors offer excellent performance for an increasing number of sensing applications in healthcare, smart homes, and the automotive sector. Having access to low-cost, miniaturized, energy efficient light sources is of critical importance for the monolithic integration of MIR sensors. Here, we present an on-chip broadband thermal MIR source fabricated by combining a complementary metal oxide semiconductor (CMOS) micro-hotplate with a dielectric-encapsulated carbon nanotube (CNT) blackbody layer. The micro-hotplate was used during fabrication as a micro-reactor to facilitate high temperature (>700 [Formula: see text]C) growth of the CNT layer and also for post-growth thermal annealing. We demonstrate, for the first time, stable extended operation in air of devices with a dielectric-encapsulated CNT layer at heater temperatures above 600 [Formula: see text]C. The demonstrated devices exhibit almost unitary emissivity across the entire MIR spectrum, offering an ideal solution for low-cost, highly-integrated MIR spectroscopy for the Internet of Things.

摘要

在许多社会经济和工业因素的推动下,气体传感器市场正在快速增长。中红外(MIR)气体传感器在医疗保健、智能家居和汽车领域越来越多的传感应用中表现出卓越的性能。对于MIR传感器的单片集成而言,获得低成本、小型化、节能的光源至关重要。在此,我们展示了一种片上宽带热MIR光源,它是通过将互补金属氧化物半导体(CMOS)微热板与介电封装的碳纳米管(CNT)黑体层相结合而制造的。在制造过程中,微热板用作微反应器,以促进CNT层的高温(>700 [公式:见正文]°C)生长,并用于生长后的热退火。我们首次证明,在加热器温度高于600 [公式:见正文]°C的情况下,具有介电封装CNT层的器件在空气中能够稳定地长时间运行。所展示的器件在整个MIR光谱范围内表现出几乎单一的发射率,为物联网的低成本、高度集成的MIR光谱学提供了理想的解决方案。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6eda/8616948/5e3fe72c474f/41598_2021_2121_Fig1_HTML.jpg

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