Ozone control strategies for local formation- and regional transport-dominant scenarios in a manufacturing city in southern China.

Given the leveling off of fine particulate matter (PM), ground-level ozone (O) pollution has become one of the most significant atmospheric pollution issues in the Pearl River Delta (PRD) region in China, especially in the manufacturing city of Dongguan, which faces more severe O pollution. The development of strategies to control O precursor emissions, including volatile organic compounds (VOCs) and nitrogen oxide (NO), depends to a large extent on the source region of the O pollution. In this study, by combining the Weather Research and Forecasting model coupled with chemistry (WRF-Chem), the Empirical Kinetic Modeling Approach (EKMA), and the Flexible Particle model (FLEXPART), more effective strategies of controlling O precursor emissions were identified under two typical types of O pollution episodes: local formation (LF)-dominant (8-12 September 2019) and regional transport (RT)-dominant (23-27 October 2017) episodes, distinguished by the WRF-FLEXPART model. During the LF-dominant episode, the EKMA revealed that the O formation in Dongguan was in a transitional regime, and the abatement of solvent use-VOCs emissions in the key area of Dongguan was more effective in reducing O levels, with an emission reduction benefit 1.7 times that of total VOCs emission sources throughout Dongguan. With respect to the RT-dominant episode, the reduction in VOCs emissions in the local region did not effectively curb O pollution, although the photochemical regime of the O formation in Dongguan was VOCs-limited. A 50% reduction in NO emissions in the upwind regions (parts of Guangzhou and Huizhou) effectively decreased the O concentration in Dongguan by 17%. The results of this study emphasize the importance of the source region of O pollution in the implementation of effective O control strategies and provide valuable insights for region-specific precursor emission policy formulation, not only in Dongguan, but also in other regions facing severe O pollution.