Popescu Vasilica, Blaga Alexandra Cristina, Pruneanu Melinda, Cristian Irina Niculina, Pîslaru Marius, Popescu Andrei, Rotaru Vlad, Crețescu Igor, Cașcaval Dan
Department of Chemical Engineering in Textiles and Leather, Faculty of Industrial Design and Business Management, "Gheorghe Asachi" Technical University of Iasi, 700050 Iasi, Romania.
Department of Organic, Biochemical and Food Engineering, "Cristofor Simionescu" Faculty of Chemical Engineering and Environmental Protection, "Gheorghe Asachi" Technical University of Iasi, 700050 Iasi, Romania.
Polymers (Basel). 2021 Nov 9;13(22):3867. doi: 10.3390/polym13223867.
The beetroot peels can be a sustainable source of betalains that can dye the wool materials through green processes based on low water and energy consumption. Green chemistry in the extraction of betalains from colored food waste/peels from red beetroot involved the use of water as a solvent, without other additives. In order for the extract obtained to be able to dye the wool, it was necessary to functionalize betalains or even the wool. Three types of sustainable functionalizations were performed, with (1) acetic acid; (2) ethanol; and (3) arginine. For each functionalization, the mechanism that can justify dyeing the wool in intense colors was elucidated. The characterization of the extract was performed with the data provided by UV-VIS and HPLC-MS analyses. The characterization of the wool dyed with the extract obtained from the red beetroot peels was possible due to the information resulting from the FTIR and CIELab analyses. The functionalizations of betalains and wool in acid environments lead to the most intense red colors. The color varies depending on the pH and the concentration of betalains.
甜菜根皮可以成为一种可持续的甜菜色素来源,通过基于低水耗和低能耗的绿色工艺为羊毛材料染色。从红甜菜根的有色食品废料/皮中提取甜菜色素的绿色化学方法涉及使用水作为溶剂,不添加其他添加剂。为了使得到的提取物能够为羊毛染色,有必要对甜菜色素甚至羊毛进行功能化处理。进行了三种类型的可持续功能化处理,分别是:(1)用乙酸;(2)用乙醇;(3)用精氨酸。对于每种功能化处理,都阐明了能够使羊毛染成鲜艳颜色的机理。提取物的表征通过紫外可见光谱(UV-VIS)和高效液相色谱-质谱联用(HPLC-MS)分析提供的数据进行。由于傅里叶变换红外光谱(FTIR)和CIELab分析得到的信息,用红甜菜根皮提取物染色的羊毛得以表征。在酸性环境中对甜菜色素和羊毛进行功能化处理会产生最深的红色。颜色会因pH值和甜菜色素浓度的不同而变化。