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将废弃聚对苯二甲酸乙二酯(PET)聚合物转化为活性炭及其生产绿色燃料的可行性。

Conversion of Waste Polyethylene Terephthalate (PET) Polymer into Activated Carbon and Its Feasibility to Produce Green Fuel.

作者信息

Ahangar Firdous Ahmad, Rashid Umer, Ahmad Junaid, Tsubota Toshiki, Alsalme Ali

机构信息

Institute of Nanoscience and Nanotechnology (ION2), University Putra Malaysia (UPM), Serdang 43400, Selangor, Malaysia.

Faculty of Science and Technology, Free University Bozen-Bolzano, Piazza Universita 5, 39100 Bolzano, Italy.

出版信息

Polymers (Basel). 2021 Nov 16;13(22):3952. doi: 10.3390/polym13223952.

Abstract

In this study, a novel idea was proposed to convert the polyethylene terephthalate (PET) waste drinking-water bottles into activated carbon (AC) to use for waste cooking oil (WCO) and palm fatty acid distillate (PFAD) feasibility to convert into esters. The acidic and basic char were prepared by using the waste PET bottles. The physiochemical properties were determined by employing various analytical techniques, such as field emission scanning electron microscopy (FESEM), thermogravimetric analysis (TGA), Fourier transform infrared (FTIR), Brunauer-Emmett-Teller (BET) and temperature-programmed desorption - ammonia/carbon dioxide (TPD-NH/CO). The prepared PET HPO and PET KOH showed the higher surface area, thus illustrating that the surface of both materials has enough space for impregnation of foreign precursors. The TPD-NH and TPD-CO results depicted that PET HPO is found to have higher acidity, i.e., 18.17 mmolg, due to the attachment of phosponyl groups to it during pretreatment, whereas, in the case of PET KOH, the basicity increases to 13.49 mmolg. The conversion results show that prepared materials can be used as a support for an acidic and basic catalyst for the conversion of WCO and PFAD into green fuel.

摘要

在本研究中,提出了一种新颖的想法,即将聚对苯二甲酸乙二酯(PET)废饮用水瓶转化为活性炭(AC),用于将废食用油(WCO)和棕榈脂肪酸馏出物(PFAD)转化为酯的可行性研究。利用废PET瓶制备了酸性和碱性炭。通过多种分析技术测定其理化性质,如场发射扫描电子显微镜(FESEM)、热重分析(TGA)、傅里叶变换红外光谱(FTIR)、布鲁诺尔-埃米特-泰勒(BET)以及程序升温脱附-氨/二氧化碳(TPD-NH/CO)。制备的PET HPO和PET KOH显示出较高的比表面积,这表明两种材料的表面有足够的空间用于浸渍外来前驱体。TPD-NH和TPD-CO结果表明,由于预处理过程中膦酰基附着在PET HPO上,其酸度较高,即18.17 mmol/g,而对于PET KOH,其碱度增加到13.49 mmol/g。转化结果表明,制备的材料可作为酸性和碱性催化剂的载体,用于将WCO和PFAD转化为绿色燃料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/da24/8625594/d25d99b34cf8/polymers-13-03952-g001.jpg

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