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生物质升级的洞察:5-羟甲基糠醛(HMF)加氢制备 2,5-二甲基呋喃(DMF)的综述。

Insight into Biomass Upgrade: A Review on Hydrogenation of 5-Hydroxymethylfurfural (HMF) to 2,5-Dimethylfuran (DMF).

机构信息

Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, Serdang 43400, Malaysia.

College of Engineering, Universiti Malaysia Pahang, Gambang, Kuantan 26300, Malaysia.

出版信息

Molecules. 2021 Nov 13;26(22):6848. doi: 10.3390/molecules26226848.

Abstract

Recent developments in the transformation of biobased 5-hydroxymethylfurfural (HMF) into a potential liquid fuel, 2,5-dimethylfuran (DMF), are summarised. This review focuses briefly on the history of HMF conversion to DMF in terms of the feedstock used and emphasises the ideal requirements in terms of the catalytic properties needed in HMF transformation into DMF. The recent state of the art and works on HMF transformation into DMF are discussed in comparison to noble metals and non-noble metals as well as bimetallic catalysts. The effect of the support used and the reaction conditions are also discussed. The recommendations for future work and challenges faced are specified.

摘要

简要总结了生物基 5-羟甲基糠醛(HMF)转化为潜在液体燃料 2,5-二甲基呋喃(DMF)的最新进展。本综述简要回顾了 HMF 转化为 DMF 的历史,包括所用原料,并强调了 HMF 转化为 DMF 所需的催化性能的理想要求。讨论了与贵金属和非贵金属以及双金属催化剂相比,HMF 转化为 DMF 的最新技术现状和工作。还讨论了所用载体的影响和反应条件。指定了对未来工作的建议和面临的挑战。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4c60/8619504/63c6025fb6ef/molecules-26-06848-g001.jpg

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