Novel Chemoresistive Sensor for Sensitive Detection of Pb Ions Using an Interdigital Gold Electrode Fabricated with a Reduced Graphene Oxide-Based Ion-Imprinted Polymer.

This study presents novel chemoresistive reduced graphene oxide-ion-imprinted polymer (IIP-rGO)-based sensors for detection of lead (Pb) ions. The ion-imprinted polymer was synthesized by bulk polymerization and modified with a variable amount of rGO incorporated to form an IIP-rGO composite. The amount of rGO in the polymer matrix affected the sensor's relative response, and 1:3 mass ratio produced excellent results, with a consistent trend as the concentration of Pb ions increased in the solution. The decrease in relative resistance (Δ/ ) followed an exponential decay relationship between the Δ/ response and the concentration of Pb ions in aqueous solutions. After solving the exponential decay function, it is observed that the sensor has the upper limit of Δ/ >1.7287 μg L, and the limit of detection of the sensor is 1.77 μg L. A nonimprinted polymer (NIP)-based sensor responded with a low relative resistance of the same magnitude although the concentration was varied. The response ratio of the IIP-based sensor to the NIP-based sensor (Δ/ )/(Δ/ ) as a function of the concentration of Pb ions in the solution shows that the response ratios recorded a maximum of around 22 at 50 μg L and then decreased as the concentration increased, following an exponential decay function with the minimum ratio of 2.09 at 200 μg L but never read 1. The sensor showed excellent selectivity against the bivalent cations Mn, Fe, Sn, and Ti. The sensor was capable of exhibiting 90% Δ/ response repeatability in a consecutive test.