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离子印迹聚合物:放射性核素的合成、表征及吸附

Ion-Imprinted Polymers: Synthesis, Characterization, and Adsorption of Radionuclides.

作者信息

Kusumkar Vipul Vilas, Galamboš Michal, Viglašová Eva, Daňo Martin, Šmelková Jana

机构信息

Department of Nuclear Chemistry, Faculty of Natural Sciences, Comenius University in Bratislava, Mlynska dolina Ilkovicova 6, 842 15 Bratislava, Slovakia.

Department of Nuclear Chemistry, Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague, Brehová 7, 115 19 Prague, Czech Republic.

出版信息

Materials (Basel). 2021 Feb 26;14(5):1083. doi: 10.3390/ma14051083.

Abstract

Growing concern over the hazardous effect of radionuclides on the environment is driving research on mitigation and deposition strategies for radioactive waste management. Currently, there are many techniques used for radionuclides separation from the environment such as ion exchange, solvent extraction, chemical precipitation and adsorption. Adsorbents are the leading area of research and many useful materials are being discovered in this category of radionuclide ion separation. The adsorption technologies lack the ability of selective removal of metal ions from solution. This drawback is eliminated by the use of ion-imprinted polymers, these materials having targeted binding sites for specific ions in the media. In this review article, we present recently published literature about the use of ion-imprinted polymers for the adsorption of 10 important hazardous radionuclides-U, Th, Cs, Sr, Ce, Tc, La, Cr, Ni, Co-found in the nuclear fuel cycle.

摘要

对放射性核素对环境有害影响的日益关注推动了放射性废物管理中缓解和沉积策略的研究。目前,有许多用于从环境中分离放射性核素的技术,如离子交换、溶剂萃取、化学沉淀和吸附。吸附剂是研究的主要领域,在这类放射性核素离子分离中发现了许多有用的材料。吸附技术缺乏从溶液中选择性去除金属离子的能力。通过使用离子印迹聚合物消除了这一缺点,这些材料在介质中具有针对特定离子的靶向结合位点。在这篇综述文章中,我们展示了最近发表的关于使用离子印迹聚合物吸附核燃料循环中发现的10种重要有害放射性核素——铀、钍、铯、锶、铈、锝、镧、铬、镍、钴——的文献。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1d8a/7956459/c014c799062b/materials-14-01083-g001.jpg

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