Kim Andrew, Hak Kim Jong, Patel Rajkumar
Department of Chemical Engineering, The Cooper Union for the Advancement of Science and Art, New York City, NY 10003, USA.
Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul 03722, South Korea.
Bioresour Technol. 2022 Feb;345:126501. doi: 10.1016/j.biortech.2021.126501. Epub 2021 Dec 7.
This review addresses composite membranes used for wastewater treatment, focusing heavily on the anti-biofouling properties of such membranes. Biofouling caused by the development of a thick biofilm on the membrane surface is a major issue that reduces water permeance and reduces its lifetime. Biofilm formation and adhesion are mitigated by modifying membranes with two-dimensional or zero-dimensional carbon-based nanomaterials or their modified substituents. In particular, nanomaterials based on graphene, including graphene oxide and carbon quantum dots, are mainly used as nanofillers in the membrane. Functionalization of the nanofillers with various organic ligands or compositing the nanofiller with other materials, such as silver nanoparticles, enhances the bactericidal ability of composite membranes. Moreover, such membrane modifications reduce biofilm adhesion while increasing water permeance and salt/dye rejection. This review discusses the recent literature on developing graphene oxide-based and carbon quantum dot-based composite membranes for biofouling-resistant wastewater treatment.
本综述探讨了用于废水处理的复合膜,重点关注此类膜的抗生物污染特性。膜表面形成厚厚的生物膜所导致的生物污染是一个主要问题,它会降低水通量并缩短膜的使用寿命。通过用二维或零维碳基纳米材料或其改性取代基对膜进行改性,可以减轻生物膜的形成和附着。特别是,基于石墨烯的纳米材料,包括氧化石墨烯和碳量子点,主要用作膜中的纳米填料。用各种有机配体对纳米填料进行功能化,或将纳米填料与其他材料(如银纳米颗粒)复合,可增强复合膜的杀菌能力。此外,这种膜改性在增加水通量和盐/染料截留率的同时,还能减少生物膜的附着。本综述讨论了近期关于开发用于抗生物污染废水处理的氧化石墨烯基和碳量子点基复合膜的文献。