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用于寿命终期管理的生物复合材料手机壳的实验室及现场规模生物降解性评估

Laboratory and field scale biodegradability assessment of biocomposite cellphone cases for end-of-life management.

作者信息

Dilawar Hina, Eskicioglu Cigdem

机构信息

UBC Bioreactor Technology Group, School of Engineering, University of British Columbia Okanagan Campus, Kelowna, British Columbia V1V 1V7, Canada.

UBC Bioreactor Technology Group, School of Engineering, University of British Columbia Okanagan Campus, Kelowna, British Columbia V1V 1V7, Canada.

出版信息

Waste Manag. 2022 Feb 1;138:148-157. doi: 10.1016/j.wasman.2021.11.033. Epub 2021 Dec 9.

Abstract

The increase in production of biobased plastics as a replacement for fossil fuel-based plastics has created the need for studies to assess their degradation under various conditions. However, developing reliable laboratory and field-testing protocols for biobased materials and products still requires extensive research. In this study, the biodegradability of a biocomposite consumer product, smart cellphone case, was determined under laboratory scale anaerobic (38 °C) and composting assays (58 °C) as well as under field scale (60-67 °C) composting conditions. The laboratory scale composting assay was conducted for 46 days using cellphone cases with dimensions of 7 × 3.5 × 0.2 and 4.6 × 3.5 × 0.2 cm, which achieved approximately 20% biodegradation. The field scale composting conditions achieved 55% weight loss of cellphone cases in 80 days. The subsequent anaerobic biodegradation assays contained three different sized (grinded, cut into 2 × 2 × 0.2 and 4 × 4 × 0.2 cm pieces) biocomposite cellphone cases conducted under mesophilic conditions for 169 days. Among the conditions tested, the size of cellphone cases did not cause a significant difference in biodegradation under anaerobic conditions. Anaerobic digestion conditions yielded only 6-8% biodegradation, which was significantly lower than that of composting. The results agree with literature on conventional waste streams stating that aerobic microbial processes are more effective to break down complex substrates, similar to biocomposite cellphone cases tested, than their anaerobic counterparts.

摘要

作为化石燃料基塑料的替代品,生物基塑料产量的增加使得有必要开展研究以评估其在各种条件下的降解情况。然而,为生物基材料和产品制定可靠的实验室和现场测试方案仍需要大量研究。在本研究中,对一种生物复合消费品——智能手机壳,在实验室规模的厌氧(38°C)和堆肥试验(58°C)以及现场规模(60 - 67°C)堆肥条件下测定其生物降解性。实验室规模的堆肥试验使用尺寸为7×3.5×0.2厘米和4.6×3.5×0.2厘米的手机壳进行了46天,实现了约20%的生物降解。现场规模的堆肥条件下,手机壳在80天内重量损失了55%。随后的厌氧生物降解试验包含三种不同尺寸(研磨、切成2×2×0.2厘米和4×4×0.2厘米的小块)的生物复合手机壳,在中温条件下进行了169天。在所测试的条件中,手机壳的尺寸在厌氧条件下对生物降解没有显著差异。厌氧消化条件下仅产生6 - 8%的生物降解,显著低于堆肥条件。该结果与关于传统废物流的文献一致,表明需氧微生物过程比厌氧过程更有效地分解复杂底物,类似于所测试的生物复合手机壳。

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