Simple and Green Synthesis of Carbonized Polymer dots from Nylon 66 Waste Fibers and its Potential Application.

Carbonized polymer dots (CPDs) have attracted widespread attention owing to their unique properties and are usually prepared from monomers of polymers or polymers. To reduce the waste of high-value petropolymers and environmental pollution, a simple and green method for the preparation of CPDs using a hydrothermal technique based on the cross-linking enhanced emission effect was proposed, in which nylon 66 waste fibers were used as a precursor and glutaraldehyde as a cross-linking agent. The as-prepared CPDs possessed polymer/carbon hybrid structures with a 3.5 nm average diameter, and hydroxyl (-OH), carboxyl (-COOH), and amino (-NH) groups were present on the surface of CPDs. It can be found that the as-prepared CPDs display excitation-dependent photoluminescence emission, which is mainly attributed to the molecular state luminescence center. Because the molecular state fluorescence of CPDs could be affected by the presence of Fe and the change of pH values, the as-prepared CPDs can be used as a probe for the detection of the concentration of Fe and the pH variations of solution. The fluorescence intensity of CPDs was selectively quenched by Fe in the range from 1 to 145 μM. In virtue of the static quenching of CPDs by Fe, a sensing system was fabricated for the quantitative detection of Fe, and its limit of detection was 0.1 μM. Based on the electrostatic doping/charging of CPDs, a pH sensor was fabricated. It showed that the fluorescence intensity of CPDs decreased along with the increase of pH from 2.60 to 12.6. What is more, the CPDs were found to be an alternative to traditional fluorescent inks for encryption and information storage.