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环保型碳量子点的合成及其作为有效吸附剂的应用。

Eco-friendly Synthesis of Carbon Quantum Dots as an Effective Adsorbent.

机构信息

Cellulose and Paper Department, National Research Centre, Cairo, 12622, Egypt.

出版信息

J Fluoresc. 2023 Mar;33(2):423-435. doi: 10.1007/s10895-022-03085-z. Epub 2022 Nov 26.

Abstract

Fluorescent carbon quantum dots (CQDs) were prepared by an economical, green, and single-step procedure with the assistance of microwave heating of urea with bagasse (SCB), cellulose (C), or carboxymethyl cellulose (CMC). The prepared CQDs were characterized using a series of spectroscopic techniques, and they had petite size, intense absorption in the UV, and excitation wavelength-dependent fluorescence. The prepared CQDs were used for Pb(II) adsorption from an aqueous solution. The removal efficiency percentages (R %) were 99.16, 96.36, and 98.48% for QCMC, QC, and QSCB, respectively. The findings validated the efficiency of CQDs synthesized from CMC, cellulose, and SCB as excellent materials for further utilization in the environmental fields of wastewater pollution detection, adsorption, and chemical sensing applications. The kinetics and isotherms studied found that all CQDs isotherms fit well with the Langmuir model than Freundlich and Temkin models. According to R, the pseudo-second-order fits the adsorption of QCMC, while the first-order one fits with QC and QSCB.

摘要

荧光碳量子点(CQDs)是通过一种经济、绿色、单步的方法制备的,在微波加热的辅助下,用甘蔗渣(SCB)、纤维素(C)或羧甲基纤维素(CMC)来实现。制备的 CQDs 采用一系列光谱技术进行了表征,它们具有小巧的尺寸、在紫外光和激发波长依赖性荧光中的强烈吸收。所制备的 CQDs 用于从水溶液中吸附 Pb(II)。对于 QCMC、QC 和 QSCB,去除效率百分比(R%)分别为 99.16%、96.36%和 98.48%。这些发现验证了从 CMC、纤维素和 SCB 合成的 CQDs 作为在废水污染检测、吸附和化学传感应用等环境领域进一步利用的优异材料的效率。研究的动力学和等温线发现,所有 CQDs 的等温线都比 Freundlich 和 Temkin 模型更符合 Langmuir 模型。根据 R,准二级模型适合 QCMC 的吸附,而一级模型适合 QC 和 QSCB。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e2b7/9957867/fef02efdbd82/10895_2022_3085_Fig1_HTML.jpg

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