Hsin Cheng-Lun, Hsiao Jen-Che, Chen You-Ming, Lee Sheng-Wei
Department of Electrical Engineering, National Central University, Taoyuan 32001, Taiwan.
Institute of Materials Science and Engineering, National Central University, Taoyuan 32001, Taiwan.
Nanotechnology. 2022 Jan 7;33(13). doi: 10.1088/1361-6528/ac4307.
Thermoelectric materials are considered promising candidates for thermal energy conversion. This study presents the fabrication of Zn- and Ce-alloyed InOwith a porous structure. The electrical conductivity was improved by the alloying effect and an ultra-low thermal conductivity was observed owing to the porous structure, which concomitantly provide a distinct enhancement of. However, SiOnanoparticle additives react with the matrix to form a third-phase impurity, which weakens the electrical conductivity and increases the thermal conductivity. A thermoelectric module was constructed for the purpose of thermal heat energy conversion. Our experimental results proved that both an enhancement in electrical conductivity and a suppression in thermal conductivity could be achieved through nano-engineering. This approach presents a feasible route to synthesize porous thermoelectric oxides, and provides insight into the effect of additives; moreover, this approach is a cost-effective method for the fabrication of thermoelectric oxides without traditional hot-pressing and spark-plasma-sintering processes.
热电材料被认为是热能转换的有前途的候选材料。本研究展示了具有多孔结构的锌和铈合金化氧化铟的制备。由于合金化效应,电导率得到提高,并且由于多孔结构观察到超低的热导率,这同时显著提高了……然而,二氧化硅纳米颗粒添加剂与基体反应形成第三相杂质,这削弱了电导率并增加了热导率。为了热能转换的目的构建了一个热电模块。我们的实验结果证明,通过纳米工程可以实现电导率的提高和热导率的抑制。这种方法为合成多孔热电氧化物提供了一条可行的途径,并深入了解了添加剂的作用;此外,这种方法是一种无需传统热压和放电等离子烧结工艺来制造热电氧化物的经济有效的方法。