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活性粒子穿越势垒的关联逃逸。

Correlated escape of active particles across a potential barrier.

机构信息

Heinrich-Heine-University of Düsseldorf, Universitätsstrasse 1, Düsseldorf, Germany.

Scuola di Scienze e Tecnologie, Università di Camerino, Via Madonna delle Carceri, I-62032 Camerino, Italy.

出版信息

J Chem Phys. 2021 Dec 21;155(23):234902. doi: 10.1063/5.0074072.

Abstract

We study the dynamics of one-dimensional active particles confined in a double-well potential, focusing on the escape properties of the system, such as the mean escape time from a well. We first consider a single-particle both in near and far-from-equilibrium regimes by varying the persistence time of the active force and the swim velocity. A non-monotonic behavior of the mean escape time is observed with the persistence time of the activity, revealing the existence of an optimal choice of the parameters favoring the escape process. For small persistence times, a Kramers-like formula with an effective potential obtained within the unified colored noise approximation is shown to hold. Instead, for large persistence times, we developed a simple theoretical argument based on the first passage theory, which explains the linear dependence of the escape time with the persistence of the active force. In the second part of the work, we consider the escape on two active particles mutually repelling. Interestingly, the subtle interplay of active and repulsive forces may lead to a correlation between particles, favoring the simultaneous jump across the barrier. This mechanism cannot be observed in the escape process of two passive particles. Finally, we find that in the small persistence regime, the repulsion favors the escape, such as in passive systems, in agreement with our theoretical predictions, while for large persistence times, the repulsive and active forces produce an effective attraction, which hinders the barrier crossing.

摘要

我们研究了一维活性粒子在双势阱中的动力学,重点研究了系统的逃逸性质,例如从势阱中平均逃逸时间。我们首先通过改变活性力的持续时间和游动速度来研究近平衡和远离平衡两种情况下的单个粒子。活性力的持续时间的变化表现出平均逃逸时间的非单调行为,揭示了存在有利于逃逸过程的参数的最优选择。对于小的持续时间,我们展示了一种基于统一色噪声近似得到的有效势的类似于 Kramers 的公式。相反,对于大的持续时间,我们基于首次通过理论提出了一个简单的理论论点,该论点解释了逃逸时间与活性力持续时间的线性关系。在工作的第二部分,我们考虑了两个相互排斥的活性粒子的逃逸。有趣的是,活性力和排斥力的微妙相互作用可能导致粒子之间的相关性,有利于同时跨越势垒。这种机制在两个被动粒子的逃逸过程中无法观察到。最后,我们发现,在小持续时间的情况下,排斥力有利于逃逸,就像在被动系统中一样,这与我们的理论预测一致,而对于大的持续时间,排斥力和活性力会产生有效的吸引力,阻碍势垒的跨越。

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