A Sulfonated Polyimide/Nafion Blend Membrane with High Proton Selectivity and Remarkable Stability for Vanadium Redox Flow Battery.

A sulfonated polyimide (SPI)/Nafion blend membrane composed of a designed and synthesized SPI polymer and the commercial Nafion polymer is prepared by a facile solution casting method for vanadium redox flow battery (VRFB). Similar molecular structures of both SPI and Nafion provide good compatibility and complementarity of the blend membrane. ATR-FTIR, H-NMR, AFM, and SEM are used to gain insights on the chemical structure and morphology of the blend membrane. Fortunately, the chemical stability of the SPI/Nafion blend membrane is effectively improved compared with reported SPI-based membranes for VRFB applications. In cycling charge-discharge tests, the VRFB with the as-prepared SPI/Nafion blend membrane shows excellent battery efficiencies and operational stability. Above results indicate that the SPI/Nafion blend membrane is a promising candidate for VRFB application. This work opens up a new possibility for fabricating high-performance SPI-based blend membrane by introduction of a polymer with a similar molecular structure and special functional groups into the SPI polymer.