He Ping, Ruan Haoda, Wang Congyang, Lu Hao
College of Mechanical and Electrical Engineering, Anhui Jianzhu University, Hefei 230601, China.
Polymers (Basel). 2021 Dec 16;13(24):4411. doi: 10.3390/polym13244411.
This study used a mechanochemical method to analyze the recycling mechanism of polyurethane foam and optimize the recycling process. The use of mechanochemical methods to regenerate the polyurethane foam powder breaks the C-O bond of the polyurethane foam and greatly enhances the activity of the powder. Based on orthogonal test design, the mesh, proportion, temperature, and time were selected to produce nine recycled boards by heat pressing. Then, the influence of four factors on the thermal conductivity and tensile strength of the recycled board was analyzed. The results show that 120 mesh polyurethane foam powder has strong activity, and the tensile strength can reach 9.913 Mpa when it is formed at 205 °C and 40 min with 50% PP powder. With the help of the low thermal conductivity of the polyurethane foam, the thermal conductivity of the recycled board can reach 0.037 W/m·K at the parameter of 40 mesh, 80%, 185 °C, 30 min. This research provides an effective method for the recycling of polyurethane foam.
本研究采用机械化学方法分析聚氨酯泡沫的回收机理并优化回收工艺。利用机械化学方法再生聚氨酯泡沫粉末会破坏聚氨酯泡沫的C-O键,大大提高粉末的活性。基于正交试验设计,选取目数、比例、温度和时间,通过热压制备九块再生板。然后,分析这四个因素对再生板导热系数和拉伸强度的影响。结果表明,120目的聚氨酯泡沫粉末活性较强,在与50%的PP粉末于205℃成型40分钟时,拉伸强度可达9.913兆帕。借助聚氨酯泡沫的低导热性,在目数40、80%、185℃、30分钟的参数下,再生板的导热系数可达到0.037瓦/米·开尔文。本研究为聚氨酯泡沫的回收提供了一种有效方法。