Ahmed Saika, Ara Gulshan, Susan Md Abu Bin Hasan
Department of Chemistry, University of Dhaka, Dhaka, 1000, Bangladesh.
Department of Chemistry, Jagannath University, Dhaka, 1100, Bangladesh.
Curr Pharm Biotechnol. 2023;24(1):118-144. doi: 10.2174/1389201023666211231100843.
In recent years, nanomaterials as photocatalysts have gained much popularity for the removal of organic pollutants from tainted water using photodegradation, since the available chemical, physical, and biological methods are often time consuming, involve high cost and dumping complications, sometimes posing serious threat to both human health and environmental elements. The use of nanomaterials is less expensive and does not, in general, form aggregated macromolecules. In addition, nanotechnology for waste-water treatment demolishes or alters the risky chemical wastes to harmless end products like HO and CO. Nanomaterials synthesized from natural resources or prepared using green synthetic routes are receiving a surge of interest as our consciousness of the ecological environment and safety rises. 'Green' materials of this kind might also show unique strength features and exceptional biodegradability, along with their other notable advantageous properties like a minimum threat to the environment, efficient recyclability and low cost compared to synthetic nanomaterials. Such green nanomaterials can also serve as nanocatalysts to treat toxic organic pollutants in a safer way, including photodegradation to less or non-toxic products. This article reviews the latest developments on the synthesis of some promising green nanomaterials aiming towards their efficient uses as photocatalysts for the degradation of organic pollutants. Strategies to find new green materials as photocatalysts through the modification of technologies and the development of novel methodologies for the safer treatment of organic pollutants will also be discussed.
近年来,纳米材料作为光催化剂在利用光降解去除受污染水中的有机污染物方面备受青睐,因为现有的化学、物理和生物方法往往耗时、成本高且存在倾倒难题,有时还会对人类健康和环境要素构成严重威胁。使用纳米材料成本较低,且一般不会形成聚集的大分子。此外,用于废水处理的纳米技术可将危险的化学废物分解或转化为无害的终产物,如H₂O和CO₂。随着我们对生态环境和安全意识的提高,由自然资源合成或采用绿色合成路线制备的纳米材料正受到越来越多的关注。这类“绿色”材料除了具有对环境威胁小、可高效回收利用以及与合成纳米材料相比成本低等其他显著优势外,还可能展现出独特的强度特性和出色的生物降解性。此类绿色纳米材料还可作为纳米催化剂,以更安全的方式处理有毒有机污染物,包括将其光降解为毒性较小或无毒的产物。本文综述了一些有前景的绿色纳米材料合成方面的最新进展,旨在高效利用它们作为光催化剂降解有机污染物。还将讨论通过改进技术和开发新型方法来寻找新型绿色光催化剂材料以更安全地处理有机污染物的策略。