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[中国浙江省中部典型硫铁矿矿区农田土壤重金属含量特征及健康风险]

[Heavy Metal Concentration Characteristics and Health Risks of Farmland Soils in Typical Pyrite Mining Area of the Central Zhejiang Province, China].

作者信息

Cheng Xiao-Meng, Sun Bin-Bin, Wu Chao, He Ling, Zeng Dao-Ming, Zhao Chen

机构信息

Institute of Geophysical & Geochemical Exploration, Chinese Academy of Geological Sciences, Langfang 065000, China.

UNESCO International Center on Global-Scale Geochemistry, Langfang 065000, China.

出版信息

Huan Jing Ke Xue. 2022 Jan 8;43(1):442-453. doi: 10.13227/j.hjkx.202102161.

Abstract

In order to ascertain the impact of pyrite mining on the surrounding farmland soil environment and human health, 42 surface soil samples (from 0-20 cm) were collected around the pyrite mining area in Longyou county. In this study, the concentrations of eight heavy metals (As, Cd, Cr, Cu, Hg, Ni, Pb, and Zn) and the pH in the topsoil were analyzed, and the concentration characteristics of heavy metals, source analysis, and human health risks assessment were studied using statistical analysis (SA), geo-accumulation index (), positive matrix factorization (PMF), and the health risk model. The average of (Cd), (Cu), (Pb), and (Zn) concentrations exceeded the background values of soils in Zhejiang province and China. According to the agricultural land pollution risk screening values (GB 15618-2018), Cd, Cu, Pb, and Zn were up to 82%, 49%, 42%, and 31%, respectively. The shows that the major pollutant element in the soils was Cd, followed by Cu, Pb, and Zn. The PMF analysis indicates that nature sources (As, Cr, and Ni), comprehensive pollution sources caused by high geological background and mining of ore-forming geological bodies (Cd, Cu, Pb, and Zn), and anthropogenic sources (Hg) were the three major sources of heavy metals in the study area, with contributions of 32%, 46%, and 22%, respectively. The results of the health risk assessment indicate that the major non-carcinogenic factor triggering risks was the ingestion of Pb; Cr exposure had carcinogenic risk for adults, and Cr and As exposure had carcinogenic risk for children.

摘要

为了确定硫铁矿开采对周边农田土壤环境和人体健康的影响,在龙游县硫铁矿开采区周边采集了42个表层土壤样本(0 - 20厘米)。本研究分析了表层土壤中8种重金属(砷、镉、铬、铜、汞、镍、铅和锌)的浓度以及pH值,并采用统计分析(SA)、地累积指数()、正定矩阵因子分解(PMF)和健康风险模型研究了重金属的浓度特征、来源分析和人体健康风险评估。镉、铜、铅和锌的平均浓度超过了浙江省和中国土壤的背景值。根据农用地土壤污染风险筛选值(GB 15618 - 2018),镉、铜、铅和锌超标率分别高达82%、49%、42%和31%。结果表明,土壤中的主要污染元素为镉,其次是铜、铅和锌。PMF分析表明,自然源(砷、铬和镍)、高地质背景和成矿地质体开采引起的综合污染源(镉、铜、铅和锌)以及人为源(汞)是研究区域重金属的三大来源,贡献率分别为32%、46%和22%。健康风险评估结果表明,引发风险的主要非致癌因素是铅的摄入;铬暴露对成年人有致癌风险,铬和砷暴露对儿童有致癌风险。

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