Ultra-thin microwave absorbers have been urgently demanded for electromagnetic applications in recent years. Herein, porous carbon with a "flower cluster" microstructure was synthesized from biomass waste (mango seeds) by a facile activation and carbonization method. The novel structure reduced the density and also improved the impedance matching, dipole polarization, and provided many carbon matrix-air interfaces for interfacial polarization, resulting in superior microwave absorption performance. At an ultra-thin thickness of 1.5 mm, extraordinary microwave absorption was achieved, with a reflection loss (RL) of -42 dB. The effective absorption bandwidth reached 4.2 GHz. The RL can be further improved to -68.4 dB by adjusting the amount of activator to manipulate the structure of porous carbon. In addition, from the simulated radar scattering results, the maximum reduction in the radar cross-section (RCS) reached 30.4 dBm, which can greatly reduce the probability of equipment being detected by radar. This work provides a low-cost and high-performance microwave absorber for electromagnetic stealth technologies.