用于高性能超级电容器的三维MXene/金属有机框架复合材料的原位生长
In Situ Growth of Three-Dimensional MXene/Metal-Organic Framework Composites for High-Performance Supercapacitors.
作者信息
Liu Chunli, Bai Yang, Li Wenting, Yang Feiyu, Zhang Guangxun, Pang Huan
机构信息
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, Jiangsu, 225009, P. R. China.
State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing, Jiangsu, 210023, P. R. China.
出版信息
Angew Chem Int Ed Engl. 2022 Mar 7;61(11):e202116282. doi: 10.1002/anie.202116282. Epub 2022 Jan 27.
In this study, we propose a versatile method for synthesizing uniform three-dimensional (3D) metal carbides, nitrides, and carbonitrides (MXenes)/metal-organic frameworks (MOFs) composites (Ti C T /Cu-BTC, Ti C T /Fe,Co-PBA, Ti C T /ZIF-8, and Ti C T /ZIF-67) that combine the advantages of MOFs and MXenes to enhance stability and improve conductivity. Subsequently, 3D hollow Ti C T /ZIF-67/CoV O composites with excellent electron- and ion-transport properties derived from Ti C T /ZIF-67 were synthesized. The specific capacitance of the Ti C T /ZIF-67/CoV O electrode was 285.5 F g , which is much higher than that of the ZIF-67 and Ti C T /ZIF-67 electrode. This study opens a new avenue for the design and synthesis of MXene/MOF composites and complex hollow structures with tailorable structures and compositions for various applications.
在本研究中，我们提出了一种通用方法来合成均匀的三维（3D）金属碳化物、氮化物和碳氮化物（MXenes）/金属有机框架（MOFs）复合材料（Ti C T /Cu-BTC、Ti C T /Fe,Co-PBA、Ti C T /ZIF-8和Ti C T /ZIF-67），该方法结合了MOFs和MXenes的优点，以提高稳定性并改善导电性。随后，合成了具有优异电子和离子传输性能的3D中空Ti C T /ZIF-67/CoV O复合材料，其源自Ti C T /ZIF-67。Ti C T /ZIF-67/CoV O电极的比电容为285.5 F g ，远高于ZIF-67和Ti C T /ZIF-67电极。本研究为设计和合成具有可定制结构和组成的MXene/MOF复合材料及复杂中空结构以用于各种应用开辟了一条新途径。
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