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纳米/微米级金属有机框架材料的合成策略与电化学研究进展

Synthesis Strategies and Electrochemical Research Progress of Nano/Microscale Metal-Organic Frameworks.

作者信息

Wang Shixian, Hu Wenhui, Ru Yue, Shi Yuxin, Guo Xiaotian, Sun Yangyang, Pang Huan

机构信息

School of Chemistry and Chemical Engineering Yangzhou University Yangzhou Jiangsu 225009 P. R. China.

出版信息

Small Sci. 2022 Oct 17;2(12):2200042. doi: 10.1002/smsc.202200042. eCollection 2022 Dec.

DOI:10.1002/smsc.202200042
PMID:40212447
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11935861/
Abstract

Nanoscale/microscale metal-organic frameworks (nano/microscale MOFs) are considered kinds of nanomaterials with profound application potentials in many fields due to the high specific surface area, permanent porosity, and multiple chemical functions. This review focuses on the specific synthesis strategies of nano/microscale MOFs, such as controlled mediation, template, one-pot, and interface growth methods, through which the shape and size of the crystal can be regulated during the nucleation process. After these targeted design and synthesis strategies, nano/microscale MOFs are optimized for energy storage, catalysis, and biomedical applications based on several merits, including a large specific surface area with more active sites, smaller ion transfer resistance, and structural stability. In addition, challenges and prospects of nano/microscale MOF materials are summarized for advanced energy storage and conversion applications.

摘要

纳米尺度/微米尺度的金属有机框架材料（纳米/微米尺度MOF）因其高比表面积、永久孔隙率和多种化学功能，被认为是在许多领域具有深远应用潜力的一类纳米材料。本综述聚焦于纳米/微米尺度MOF的特定合成策略，如可控介导法、模板法、一锅法和界面生长法，通过这些方法可以在成核过程中调控晶体的形状和尺寸。经过这些有针对性的设计和合成策略后，基于包括具有更多活性位点的大比表面积、更小的离子转移电阻和结构稳定性等优点，纳米/微米尺度MOF在能量存储、催化和生物医学应用方面得到了优化。此外，还总结了纳米/微米尺度MOF材料在先进能量存储和转换应用中的挑战与前景。

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