Preparation of Stable Phase Change Material Emulsions for Thermal Energy Storage and Thermal Management Applications: A Review.

Thermal energy storage (TES) is an important means for the conservation and efficient utilization of excessive and renewable energy. With a much higher thermal storage capacity, latent heat storage (LHS) may be more efficient than sensible heat storage. Phase change materials (PCMs) are the essential storage media for LHS. PCM emulsions have been developed for LHS in flow systems, which act as both heat transfer and thermal storage media with enhanced heat transfer, low pumping power, and high thermal storage capacity. However, two major barriers to the application of PCM emulsions are their instability and high degree of supercooling. To overcome these, various strategies have been attempted, such as the reduction of emulsion droplet size, addition of nucleating agents, and optimization of the formulation. To the best of our knowledge, however, there is still a lack of review articles on fabrication methods for PCM emulsions or their latest applications. This review was to provide an up-to-date and comprehensive summary on the effective strategies and the underlying mechanisms for the preparation of stable PCM emulsions and reduction of supercooling, especially with the organic PCMs of paraffin. It was also to share our insightful perspectives on further development and potential applications of PCM emulsions for efficient energy storage.