Terekhov Ivan V, Chistyakov Evgeniy M
Federal State Unitary Enterprise, All-Russian Scientific Research Institute of Aviation Materials, National Research Center "Kurchatov Institute", State Research Center of the Russian Federation, 17, Radio St., 105005 Moscow, Russia.
Department of Chemical Technology of Polymers, Mendeleev University of Chemical Technology of Russia, 9, Miusskaya sq., 125047 Moscow, Russia.
Polymers (Basel). 2021 Dec 27;14(1):87. doi: 10.3390/polym14010087.
Binders, or tackifiers, have become widespread in the production of new composite materials by liquid composite molding (LCM) techniques due to their ability to stabilize preforms during laying-up and impregnation, as well as to improve fracture toughness of the obtained composites, which is very important in aviation, automotive, ship manufacturing, etc. Furthermore, they can be used in modern methods of automatic laying of dry fibers into preforms, which significantly reduces the labor cost of the manufacturing process. In this article, we review the existing research from the 1960s of the 20th century to the present days in the field of creation and properties of binders used to bond various layers of preforms in the manufacturing of composite materials by LCM methods to summarize and synthesize knowledge on these issues. Different binders based on epoxy, polyester, and a number of other resins compatible with the corresponding polymer matrices are considered in the article. The influence of binders on the preforming process, various properties of obtained preforms, including compaction, stability, and permeability, as well as the main characteristics of composite materials obtained by various LCM methods and the advantages and disadvantages of this technology have been also highlighted.
粘结剂,或称增粘剂,因其能够在铺层和浸渍过程中稳定预成型体,并提高所得复合材料的断裂韧性,在通过液体复合材料成型(LCM)技术生产新型复合材料的过程中得到了广泛应用。这在航空、汽车、船舶制造等领域非常重要。此外,它们可用于将干纤维自动铺放成预成型体的现代方法中,这显著降低了制造过程的劳动力成本。在本文中,我们回顾了从20世纪60年代到现在在通过LCM方法制造复合材料时用于粘结预成型体各层的粘结剂的制备和性能领域的现有研究,以总结和综合关于这些问题的知识。本文考虑了基于环氧树脂、聚酯以及许多其他与相应聚合物基体相容的树脂的不同粘结剂。还强调了粘结剂对预成型过程的影响、所得预成型体的各种性能,包括压实性、稳定性和渗透性,以及通过各种LCM方法获得的复合材料的主要特性和该技术的优缺点。