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镁中孪晶形核与早期生长的可视化及验证

Visualization and validation of twin nucleation and early-stage growth in magnesium.

作者信息

Jiang Lin, Gong Mingyu, Wang Jian, Pan Zhiliang, Wang Xin, Zhang Dalong, Wang Y Morris, Ciston Jim, Minor Andrew M, Xu Mingjie, Pan Xiaoqing, Rupert Timothy J, Mahajan Subhash, Lavernia Enrique J, Beyerlein Irene J, Schoenung Julie M

机构信息

Department of Materials Science and Engineering, University of California, Irvine, CA, 92697, USA.

Materials & Structural Analysis Division, Thermo Fisher Scientific, Hillsboro, OR, 97124, USA.

出版信息

Nat Commun. 2022 Jan 10;13(1):20. doi: 10.1038/s41467-021-27591-z.

DOI:10.1038/s41467-021-27591-z
PMID:35013175
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8748725/
Abstract

The abrupt occurrence of twinning when Mg is deformed leads to a highly anisotropic response, making it too unreliable for structural use and too unpredictable for observation. Here, we describe an in-situ transmission electron microscopy experiment on Mg crystals with strategically designed geometries for visualization of a long-proposed but unverified twinning mechanism. Combining with atomistic simulations and topological analysis, we conclude that twin nucleation occurs through a pure-shuffle mechanism that requires prismatic-basal transformations. Also, we verified a crystal geometry dependent twin growth mechanism, that is the early-stage growth associated with instability of plasticity flow, which can be dominated either by slower movement of prismatic-basal boundary steps, or by faster glide-shuffle along the twinning plane. The fundamental understanding of twinning provides a pathway to understand deformation from a scientific standpoint and the microstructure design principles to engineer metals with enhanced behavior from a technological standpoint.

摘要

镁发生变形时孪晶的突然出现会导致高度各向异性的响应,使其在结构应用中过于不可靠,在观察中过于不可预测。在此,我们描述了一项针对具有精心设计几何形状的镁晶体的原位透射电子显微镜实验,以可视化一种长期提出但未经验证的孪晶机制。结合原子模拟和拓扑分析,我们得出结论,孪晶成核通过一种需要棱柱面-基面转变的纯重排机制发生。此外,我们验证了一种依赖于晶体几何形状的孪晶生长机制,即与塑性流动不稳定性相关的早期生长,它可以由棱柱面-基面边界台阶的较慢移动主导,也可以由沿孪晶面的较快滑移-重排主导。对孪晶的基本理解从科学角度提供了一条理解变形的途径,从技术角度提供了设计具有增强性能金属的微观结构设计原则。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1eb9/8748725/e58f2feac34b/41467_2021_27591_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1eb9/8748725/a8ea6d07dbe1/41467_2021_27591_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1eb9/8748725/bd48d5111cf9/41467_2021_27591_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1eb9/8748725/6b9a3c13f77c/41467_2021_27591_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1eb9/8748725/07ac36178fec/41467_2021_27591_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1eb9/8748725/e58f2feac34b/41467_2021_27591_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1eb9/8748725/a8ea6d07dbe1/41467_2021_27591_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1eb9/8748725/bd48d5111cf9/41467_2021_27591_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1eb9/8748725/6b9a3c13f77c/41467_2021_27591_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1eb9/8748725/07ac36178fec/41467_2021_27591_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/1eb9/8748725/e58f2feac34b/41467_2021_27591_Fig5_HTML.jpg

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本文引用的文献

1
Direct observation of dual-step twinning nucleation in hexagonal close-packed crystals.六方密堆积晶体中双步孪晶成核的直接观察
Nat Commun. 2020 May 18;11(1):2483. doi: 10.1038/s41467-020-16351-0.
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Disclinations and disconnections in minerals and metals.矿物和金属中的位错和连接缺失。
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High dislocation density-induced large ductility in deformed and partitioned steels.变形和分区钢中高位错密度诱导的高延展性。
用于纳米尺度化学动力学的时间分辨透射电子显微镜。
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Clustering on Magnesium Surfaces - Formation and Diffusion Energies.镁表面的聚类 - 形成能和扩散能。
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Mechanism and energetics of 〈c + a〉 dislocation cross-slip in hcp metals.六方密排金属中〈c + a〉位错交滑移的机制与能量学
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