Department of Chemistry, School of Sciences, Gujarat University, Ahmedabad, 380009, Gujarat, India.
J Fluoresc. 2022 Mar;32(2):583-592. doi: 10.1007/s10895-021-02858-2. Epub 2022 Jan 11.
Identification and detection of harmful contaminants such as nickel and other materials from soil and water is critical necessity at the present moment. So with this motive to detect and identify harmful pollutants, a novel cyclotriveratrylene based derivative was prepared for the detection and binding of harmful pollutants which had the properties of fluorescence. The newly derivative of Cyclotriveratrylene was found to be highly sensitive and selective towards Ni ions. The complexation behaviour of this newly synthesised molecule was studied in presence of transition elements. Also computational methods such as docking, molecular modelling and DFT were used to study the molecular orbitals and energies of CTG-NBEP. The detection of Ni from water samples were also carried out successfully.
目前，识别和检测土壤和水中的有害污染物（如镍和其他物质）是至关重要的。因此，出于检测和识别有害污染物的目的，我们制备了一种新型基于环三亚苯的衍生物，用于检测和结合具有荧光性质的有害污染物。研究发现，新合成的环三亚苯衍生物对 Ni 离子具有高灵敏度和选择性。还研究了该新合成分子在过渡金属存在下的络合行为。此外，还使用计算方法（如对接、分子建模和 DFT）来研究 CTG-NBEP 的分子轨道和能量。还成功地从水样中检测到了 Ni。
