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利用^1Na 核磁共振光谱法对几种食品中钠离子结合状态的特性进行研究。

Characterization of the sodium binding state in several food products by Na nuclear magnetic resonance spectroscopy.

机构信息

UR QuaPA, INRAE, Saint-Gènes-Champanelle, France.

PROBE Research Infrastructure, AgroResonance Facility, INRAE, Saint-Genès-Champanelle, France.

出版信息

Magn Reson Chem. 2022 Jul;60(7):597-605. doi: 10.1002/mrc.5250. Epub 2022 Feb 21.

Abstract

In food, salt has several key roles including conservative and food perception. For this latter, it is well-known that the interaction of sodium with the food matrix modifies the consumer perception. It is then critical to characterize these interactions in various real foods. For this purpose, we exploited the information obtained on both single and double quantum Na nuclear magnetic resonance (NMR) spectroscopies. All salted food samples studied showed strong interactions with the food matrix leading to quadrupolar interactions. However, for some of them, the single quantum analysis did not match the theoretical prediction. This was explained by the presence of another type of sodium population, which did not produce quadrupolar interactions. This finding is of critical importance to perform quantitative magnetic resonance imaging (MRI) and to understand the consumer salty taste perception.

摘要

在食品中,盐有几个关键作用,包括保存和食物感知。对于后者,众所周知,钠与食物基质的相互作用会改变消费者的感知。因此,在各种实际食品中对这些相互作用进行特征描述是至关重要的。为此,我们利用了单量子和双量子钠核磁共振(NMR)光谱学获得的信息。研究的所有加盐食品样品都与食物基质表现出强烈的相互作用,导致了四极相互作用。然而,对于其中一些样品,单量子分析与理论预测不匹配。这可以通过存在另一种类型的不产生四极相互作用的钠群体来解释。这一发现对于进行定量磁共振成像(MRI)和理解消费者的咸味感知至关重要。

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