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采用榅桲提取物的环保型钴锌铁氧体的合成及其在吸附和催化方面的应用:一种环境修复的方法。

Eco-friendly synthesis of cobalt-zinc ferrites using quince extract for adsorption and catalytic applications: An approach towards environmental remediation.

机构信息

Department of Chemistry, Vasyl Stefanyk Precarpathian National University, 57 Shevchenko Street, 76018, Ivano-Frankivsk, Ukraine; School of Science and Technology, Glocal University, Saharanpur, India.

Educational and Scientific Center of Materials Science and Nanotechnology, Vasyl Stefanyk Precarpathian National University, Ivano-Frankivsk, 76018, Ukraine.

出版信息

Chemosphere. 2022 May;294:133565. doi: 10.1016/j.chemosphere.2022.133565. Epub 2022 Jan 15.


DOI:10.1016/j.chemosphere.2022.133565
PMID:35041818
Abstract

Cobalt-zinc ferrite nanoparticles were synthesized using environmentally friendly approach with quince extract as a reducing agent. Crystal structure and morphology of the obtained materials were studied by XRD, SEM-EDS, Mössbauer and IR spectroscopy. The synthesized nanoparticles have a cubic spinel structure and crystallite size ranging from 5 to 9 nm. The infrared spectra contain characteristic absorption bands for the M-O (∼560 cm) and M-O bonds (∼420 cm). Force constants were calculated for both tetrahedral and octahedral bonds. As the Co content increases, the force constant for the tetrahedral bond increases and the force constant for the octahedral bond decreases. The obtained ferrite nanoparticles have good magnetization as shown by VSM (in the range from 36 to 67 emu/g). Magnetic nanoparticles CoZnFeO were also tested for induction heating with electromagnetic field. The sample with x (Co) = 0.4 has the highest specific absorption rate. The synthesized samples were tested as adsorbents using the Congo Red dye as model pollutant. The best adsorbent was pure zinc ferrite with the adsorption capacity of 24.7 mg/g. The catalytic activity of the obtained ferrites for the decomposition of HO was studied as well. The most active catalyst was pure cobalt ferrite. Probably, the active centers are octahedral cobalt ions. Thus, the obtained magnetic nanoparticles can be used for the adsorptive removal of pollutants, catalytic decomposition of the HO and low-frequency hyperthermia.

摘要

钴锌铁氧体纳米粒子采用环境友好的方法合成,使用榅桲提取物作为还原剂。采用 XRD、SEM-EDS、穆斯堡尔和红外光谱研究了所得材料的晶体结构和形态。合成的纳米粒子具有立方尖晶石结构,晶粒尺寸在 5 到 9nm 之间。红外光谱包含 M-O(560cm)和 M-O 键(420cm)的特征吸收带。计算了四面体和八面体键的力常数。随着 Co 含量的增加,四面体键的力常数增加,而八面体键的力常数减小。所获得的铁氧体纳米粒子具有良好的磁化性能,如 VSM 所示(在 36 到 67 emu/g 范围内)。还使用电磁场对 CoZnFeO 磁性纳米粒子进行了感应加热测试。具有 x(Co)=0.4 的样品具有最高的比吸收率。对合成的样品进行了以刚果红染料为模型污染物的吸附剂测试。纯锌铁氧体的吸附容量最高,为 24.7mg/g。还研究了所得到的铁氧体对 HO 分解的催化活性。最活跃的催化剂是纯钴铁氧体。可能,活性中心是八面体钴离子。因此,所得到的磁性纳米粒子可用于污染物的吸附去除、HO 的催化分解和低频热疗。

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引用本文的文献

[1]
Progress in the Preparation and Modification of Zinc Ferrites Used for the Photocatalytic Degradation of Organic Pollutants.

Int J Environ Res Public Health. 2022-8-28

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