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锌和钴铁氧体纳米粒子:朝着传感和吸附研究的应用发展。

Zn and Co ferrite nanoparticles: towards the applications of sensing and adsorption studies.

机构信息

Department of Chemistry, School of Advanced Sciences, KLE Technological University, BVB Campus, Hubbalii, Vidyanagar, 580031, India.

Department of Chemistry and Research Center, NMKRV College for Women, Jayanagar, Bangalore, 560011, India.

出版信息

Environ Sci Pollut Res Int. 2023 May;30(25):66994-67007. doi: 10.1007/s11356-023-27201-z. Epub 2023 Apr 26.

Abstract

An important deliberation of this current work is the impending applications of bivalent transition metals doped with nano ferrites and to study their emerging properties of magnetically active ferrites, which constitute oxides of iron (different conformers most demanding γ-FeO) and transition metal complexes of bivalent metal oxides like cobalt (Co(II)) and magnesium (Mg(II)). Fe ions occupy tetrahedral sites; the rest of Fe and the Co ions occupy octahedral sites. For the synthesis, a self-propagating method of combustion at lower temperature was used. Zinc and cobalt nano ferrites are synthesized from the chemical coprecipitation method of 20 to 90 nm in average size, characterized thoroughly employing FTIR and PXRD and surface morphology studied using SEM. These results explain the existence of ferrite nanoparticles in cubic spinel. Magnetically active metal oxide nanoparticles are now commonly employed in main studies of sensing, absorption, and other properties. All studies showed the interesting results.

摘要

本研究工作的一个重要讨论点是二价过渡金属掺杂纳米铁氧体的即将应用,并研究它们作为具有磁性的铁氧体的新兴特性,这些铁氧体由铁的氧化物(不同构象体中最需要的γ-FeO)和二价金属氧化物的过渡金属配合物组成,如钴(Co(II))和镁(Mg(II))。Fe 离子占据四面体位置;其余的 Fe 和 Co 离子占据八面体位置。对于合成,使用较低温度的自蔓延燃烧法。锌和钴纳米铁氧体是通过平均尺寸为 20 至 90nm 的化学共沉淀法合成的,使用 FTIR 和 PXRD 进行了全面的特性分析,并使用 SEM 研究了表面形态。这些结果解释了立方尖晶石中存在铁氧体纳米粒子。目前,具有磁性的金属氧化物纳米粒子通常用于传感、吸收和其他性质的主要研究中。所有研究都显示出了有趣的结果。

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