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深部地壳硫化物熔体的运移作为岩石圈上部成矿作用的一级控制因素。

Mobilisation of deep crustal sulfide melts as a first order control on upper lithospheric metallogeny.

作者信息

Holwell David A, Fiorentini Marco L, Knott Thomas R, McDonald Iain, Blanks Daryl E, Campbell McCuaig T, Gorczyk Weronika

机构信息

Centre for Sustainable Resource Extraction, School of Geography, Geology and the Environment, University of Leicester, University Road, Leicester, LE1 7RH, UK.

Centre for Exploration Targeting, School of Earth Sciences, ARC Centre of Excellence in Core to Crust Fluid Systems, University of Western Australia, 35 Stirling Highway, Crawley, WA, 6009, Australia.

出版信息

Nat Commun. 2022 Jan 31;13(1):573. doi: 10.1038/s41467-022-28275-y.

Abstract

Magmatic arcs are terrestrial environments where lithospheric cycling and recycling of metals and volatiles is enhanced. However, the first-order mechanism permitting the episodic fluxing of these elements from the mantle through to the outer Earth's spheres has been elusive. To address this knowledge gap, we focus on the textural and minero-chemical characteristics of metal-rich magmatic sulfides hosted in amphibole-olivine-pyroxene cumulates in the lowermost crust. We show that in cumulates that were subject to increasing temperature due to prolonged mafic magmatism, which only occurs episodically during the complex evolution of any magmatic arc, Cu-Au-rich sulfide can exist as liquid while Ni-Fe rich sulfide occurs as a solid phase. This scenario occurs within a 'Goldilocks' temperature zone at ~1100-1200 °C, typical of the base of the crust in arcs, which permits episodic fractionation and mobilisation of Cu-Au-rich sulfide liquid into permeable melt networks that may ascend through the lithosphere providing metals for porphyry and epithermal ore deposits.

摘要

岩浆弧是陆地环境,在那里金属和挥发物的岩石圈循环和再循环得到增强。然而,允许这些元素从地幔间歇性地流入地球外层球体的一级机制一直难以捉摸。为了填补这一知识空白,我们专注于最下部地壳中角闪石-橄榄石-辉石堆积物中所含富金属岩浆硫化物的结构和矿物化学特征。我们表明,在因长期镁铁质岩浆作用而温度不断升高的堆积物中(这种情况仅在任何岩浆弧的复杂演化过程中间歇性发生),富含铜金的硫化物可以呈液态存在,而富含镍铁的硫化物则以固相形式出现。这种情况发生在一个约1100 - 1200°C的“ Goldilocks”温度区内,这是弧地壳底部的典型温度,它允许富含铜金的硫化物液体间歇性分馏并迁移到可渗透的熔体网络中,这些熔体网络可能会穿过岩石圈上升,为斑岩和浅成热液矿床提供金属。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d0a1/8803977/95cab3df148b/41467_2022_28275_Fig1_HTML.jpg

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