α-亚氨基铑卡宾引发的 1,2-酰基迁移反应构建取代的 1-萘酚
1,2-Acyl migration with α-imino rhodium carbenoids leading to substituted 1-naphthols.
机构信息
Department of Synthetic Chemistry and Biological Chemistry, Kyoto University, Katsura, Kyoto 615-8510, Japan.
出版信息
Chem Commun (Camb). 2022 Feb 22;58(16):2710-2713. doi: 10.1039/d1cc06349a.
PMID:35112676
Abstract
A unique method for the synthesis of substituted 1-naphthols by a rhodium(II)-catalysed ring-expansion reaction of 2-triazolyl-1-indanone derivatives is reported. 1,2-Acyl migration occurs with an intermediate α-imino rhodium carbenoid generated from the triazolyl moiety.
摘要
报道了一种通过铑（II）催化 2-三唑基-1-茚酮衍生物的环扩张反应合成取代的 1-萘酚的独特方法。1,2-酰基迁移发生在中间体α-亚氨基铑卡宾从三唑部分生成。
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