Corcé Vincent, Ollivier Cyril, Fensterbank Louis
Sorbonne Université, CNRS, Institut Parisien de Chimie Moléculaire - 4 Place Jussieu, CC 229, F-75252 Paris Cedex 05, France.
Chem Soc Rev. 2022 Feb 21;51(4):1470-1510. doi: 10.1039/d1cs01084k.
Recent developments in the use of boron, silicon, nitrogen and sulfur derivatives in single-electron transfer reactions for the generation of alkyl radicals are described. Photoredox catalyzed, electrochemistry promoted or thermally-induced oxidative and reductive processes are discussed highlighting their synthetic scope and discussing their mechanistic pathways.
本文描述了硼、硅、氮和硫衍生物在单电子转移反应中用于生成烷基自由基的最新进展。讨论了光氧化还原催化、电化学促进或热诱导的氧化和还原过程，突出了它们的合成范围并探讨了其反应机理。
