Marotta Alessandro, Adams Callum E, Molloy John J
Department of Biomolecular Systems, Max-Planck-Institute of Colloids and Interfaces, Am Mühlenberg 1, 14476, Potsdam, Germany.
Angew Chem Int Ed Engl. 2022 Sep 19;61(38):e202207067. doi: 10.1002/anie.202207067. Epub 2022 Aug 10.
Recently the fruitful merger of organoboron chemistry and photocatalysis has come to the forefront of organic synthesis, resulting in the development of new technologies to access complex (non)borylated frameworks. Central to the success of this combination is control of boron hybridisation. Contingent on the photoactivation mode, boron as its neutral planar form or tetrahedral boronate can be used to regulate reactivity. This Minireview highlights the current state of the art in photocatalytic processes utilising organoboron compounds, paying particular attention to the role of boron hybridisation for the target transformation.
最近，有机硼化学与光催化的成功结合已成为有机合成的前沿领域，催生出了用于构建复杂（非）硼化骨架的新技术。这种结合成功的关键在于对硼杂化的控制。根据光活化模式，硼以其中性平面形式或四面体硼酸酯形式可用于调节反应活性。本综述重点介绍了利用有机硼化合物的光催化过程的当前技术水平，特别关注硼杂化在目标转化中的作用。
