铜催化的环状二芳基碘鎓盐与酰亚胺的不对称开环反应。
Copper-Catalyzed Asymmetric Ring-Opening Reaction of Cyclic Diaryliodonium Salts with Imides.
机构信息
School of Pharmacy & State Key Laboratory of Applied Organic Chemistry & Collaborative Innovation Center for Northwestern Chinese Medicine, Lanzhou University, Room 609, Xinglin Building, 222 Tianshui South Road, Chengguan District, Lanzhou 730000, China.
School of Chemistry and Chemical Engineering, Chongqing University, 174 Shazheng Street, Chongqing 400044, China.
出版信息
Org Lett. 2022 Feb 18;24(6):1394-1399. doi: 10.1021/acs.orglett.2c00247. Epub 2022 Feb 8.
An efficient copper-catalyzed asymmetric ring-opening reaction of diaryliodonium salts with imides has been developed, affording a wide range of axially chiral 2-imidobiaryl compounds with excellent enantioselectivities and better convertibility. The potential utility of the current method has been supported by the synthesis of two known chiral ligands with better efficiency, which would be of great significance to the development of other catalytic asymmetric reactions.
一种高效的铜催化不对称芳基碘盐与酰亚胺的开环反应已经被开发出来，为广泛的轴手性 2-亚胺联芳基化合物提供了优异的对映选择性和更好的转化率。该方法的潜在应用价值得到了两种已知手性配体的合成的支持，其效率更高，这对其他催化不对称反应的发展将具有重要意义。
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