Anis Arfat, Elnour Ahmed Yagoub, Alhamidi Abdullah, Alam Mohammad Asif, Al-Zahrani Saeed M, AlFayez Fayez, Bashir Zahir
SABIC Polymer Research Center (SPRC), Chemical Engineering Department, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia.
Center of Excellence for Research in Engineering Materials (CEREM), King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia.
Polymers (Basel). 2022 Feb 7;14(3):630. doi: 10.3390/polym14030630.
Previously, we reported that amorphous poly(ethylene terephthalate) (PET) filled with irregular nodular aluminium (Al) particles gave simultaneous increases in tensile modulus, tensile strength, and impact resistance, which is unusual for materials. Here, we investigated the effect of the particle shape and size by using nano-platelet Al. The Al nano-platelets had a thickness higher than graphenes and clays, but lower than mica and talc, and due to their large widths, they had high aspect ratios. Due to the ductility of Al, the platelets maintained the high aspect ratio and did not snap during injection moulding. In addition to avoiding the usual drop in tensile strength and impact, the composites with nano Al platelets gave an unusually high flexural modulus (8 GPa), which was almost double that attained practically with talc, mica, and graphene. This was because of the high tendency of the Al nano platelets to become oriented during moulding. The Al-PET composite would be a more cost-and-performance effective combination for making conductive composites. The Al is a cheaper material than graphene, surface treatment for adhesion (to PET) is unnecessary, and dispersion issues, such as exfoliation and de-aggregation, are not a problem.
此前,我们报道过,填充有不规则结节状铝(Al)颗粒的非晶态聚对苯二甲酸乙二酯(PET)的拉伸模量、拉伸强度和抗冲击性同时提高,这对材料来说并不常见。在此,我们使用纳米片状铝研究了颗粒形状和尺寸的影响。铝纳米片的厚度高于石墨烯和粘土,但低于云母和滑石,并且由于其宽度较大,具有高纵横比。由于铝的延展性,这些薄片在注塑成型过程中保持了高纵横比且不会折断。除了避免通常的拉伸强度和抗冲击性下降外,含有纳米铝片的复合材料还具有异常高的弯曲模量(8吉帕),几乎是实际使用滑石、云母和石墨烯时所达到值的两倍。这是因为铝纳米片在成型过程中具有很高的取向倾向。铝 - PET复合材料对于制造导电复合材料而言将是一种性价比更高的组合。铝是比石墨烯更便宜的材料,无需进行用于粘结(与PET)的表面处理,而且诸如剥落和去团聚等分散问题也不是问题。