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具有优化机械性能的可模塑导电塑料。

Mouldable Conductive Plastic with Optimised Mechanical Properties.

作者信息

Anis Arfat, Alhamidi Abdullah, Bashir Zahir, Alam Mohammad Asif, Al-Zahrani Saeed M

机构信息

SABIC Polymer Research Center (SPRC), Chemical Engineering Department, King Saud University, Riyadh 11421, Saudi Arabia.

Catenated Carbon Consultancy Ltd., 192 Wake Green Road, Birmingham B13 9QE, UK.

出版信息

Polymers (Basel). 2024 Jan 23;16(3):311. doi: 10.3390/polym16030311.

Abstract

This paper investigates making an injection mouldable conductive plastic formulation that aims for conductivity into the electromagnetic interference (EMI) shielding range, with good mechanical properties (i.e., stiffness, strength, and impact resistance). While conductivity in the range (electrostatic charge dissipation) and EMI shielding have been attained by incorporating conductive fillers such as carbon black, metals powders, and new materials, such as carbon nanotubes (CNTs), this often occurs with a drop in tensile strength, elongation-to-break resistance, and impact resistance. It is most often the case that the incorporation of high modulus fillers leads to an increase in modulus but a drop in strength and impact resistance. In this work, we have used short carbon fibres as the conductive filler and selected a 50/50 PBT/rPET (recycled PET) for the plastic matrix. Carbon fibres are cheaper than CNTs and graphenes. The PBT/rPET has low melt viscosity and crystallises sufficiently fast during injection moulding. To improve impact resistance, a styrene-ethylene-butadiene-styrene (SEBS) rubber toughening agent was added to the plastic. The PBT/rPET had very low-impact resistance and the SEBS provided rubber toughening to it; however, the rubber caused a drop in the tensile modulus and strength. The short carbon fibre restored the modulus and strength, which reached higher value than the PBT/rPET while providing the conductivity. Scanning electron microscope pictures showed quite good bonding of the current filler (CF) to the PBT/rPET. An injection mouldable conductive plastic with high conductivity and raised modulus, strength, and impact resistance could be made.

摘要

本文研究制备一种可注塑成型的导电塑料配方,其目标是使导电性达到电磁干扰(EMI)屏蔽范围,同时具备良好的机械性能(即刚度、强度和抗冲击性)。虽然通过加入导电填料(如炭黑、金属粉末以及诸如碳纳米管(CNT)等新材料)已实现了该范围内的导电性(静电电荷耗散)和EMI屏蔽,但这往往伴随着拉伸强度、断裂伸长率和抗冲击性的下降。通常情况下,加入高模量填料会导致模量增加,但强度和抗冲击性下降。在这项工作中,我们使用短碳纤维作为导电填料,并选择50/50的聚对苯二甲酸丁二醇酯/再生聚对苯二甲酸乙二酯(rPET)作为塑料基体。碳纤维比碳纳米管和石墨烯便宜。聚对苯二甲酸丁二醇酯/rPET具有低熔体粘度,并且在注塑成型过程中结晶速度足够快。为了提高抗冲击性,向塑料中添加了苯乙烯-乙烯-丁二烯-苯乙烯(SEBS)橡胶增韧剂。聚对苯二甲酸丁二醇酯/rPET的抗冲击性非常低,SEBS为其提供了橡胶增韧效果;然而,这种橡胶导致拉伸模量和强度下降。短碳纤维恢复了模量和强度,使其达到比聚对苯二甲酸丁二醇酯/rPET更高的值,同时提供了导电性。扫描电子显微镜图片显示当前填料(CF)与聚对苯二甲酸丁二醇酯/rPET之间有相当好的结合。由此可以制备出一种具有高导电性、提高的模量、强度和抗冲击性的可注塑成型导电塑料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2647/10856916/0565c2093ea9/polymers-16-00311-g008.jpg

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