Alhamidi Abdullah, Anis Arfat, Al-Zahrani Saeed M, Bashir Zahir, Alrashed Maher M
SABIC Polymer Research Center (SPRC), Chemical Engineering Department, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia.
Polymers (Basel). 2022 Mar 9;14(6):1092. doi: 10.3390/polym14061092.
Conductive plastics are made by placing conductive fillers in polymer matrices. It is known that a conductive filler in a binary polymer blend with a co-continuous morphology is more effective than in a single polymer, because it aids the formation of a 'segregated conductive network'. We embedded a relatively low-cost conductive filler, aluminium nano platelets, in a 60/40 PBT/PET polymer blend. While 25 vol.% of the Al nanoplatelets when placed in a single polymer (PET) gave a material with the resistivity of an insulator (10 Ωcm), the same Al nano platelets in the 60/40 PBT/PET blend reduced the resistivity to 7.2 × 10 Ωcm, which is in the category of an electrostatic charge dissipation material. While PET tends to give amorphous articles, the 60/40 PBT/PET blends crystallised in the time scale of the injection moulding and hence the conductive articles had dimensional stability above the T of PET.
导电塑料是通过将导电填料置于聚合物基体中制成的。众所周知,在具有共连续形态的二元聚合物共混物中的导电填料比在单一聚合物中更有效,因为它有助于形成“隔离导电网络”。我们将一种成本相对较低的导电填料——铝纳米片嵌入60/40的聚对苯二甲酸丁二醇酯/聚对苯二甲酸乙二酯(PBT/PET)聚合物共混物中。当25体积%的铝纳米片置于单一聚合物(PET)中时,得到的材料具有绝缘体的电阻率(10Ω·cm),而在60/40的PBT/PET共混物中相同的铝纳米片将电阻率降低到7.2×10Ω·cm,这属于静电耗散材料类别。虽然PET倾向于制成无定形制品,但60/40的PBT/PET共混物在注塑成型的时间尺度内结晶,因此导电制品在高于PET的玻璃化转变温度时具有尺寸稳定性。