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基于碱激发玻璃纤维废料制备的多孔玻璃微球

Porous Glass Microspheres from Alkali-Activated Fiber Glass Waste.

作者信息

Mahmoud Mokhtar, Kraxner Jozef, Kaňková Hana, Hujová Miroslava, Chen Si, Galusek Dušan, Bernardo Enrico

机构信息

FunGlass, Centre for Functional and Surface Functionalized Glass, Alexander Dubček University of Trenčín, 911 50 Trenčín, Slovakia.

Department of Industrial Engineering, University of Padova, 35131 Padova, Italy.

出版信息

Materials (Basel). 2022 Jan 28;15(3):1043. doi: 10.3390/ma15031043.

DOI:10.3390/ma15031043
PMID:35160986
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8838283/
Abstract

Fiber glass waste (FGW) was subjected to alkali activation in an aqueous solution with different concentrations of sodium/potassium hydroxide. The activated materials were fed into a methane-oxygen flame with a temperature of around 1600 °C. X-ray diffraction analysis confirmed the formation of several hydrated compounds, which decomposed upon flame synthesis, leading to porous glass microspheres (PGMs). Pore formation was favored by using highly concentrated activating alkali solutions. The highest homogeneity and yield of PGMs corresponded to the activation with 9 M KOH aqueous solution.

摘要

玻璃纤维废料(FGW)在含有不同浓度氢氧化钠/氢氧化钾的水溶液中进行碱活化处理。将活化后的材料送入温度约为1600℃的甲烷-氧气火焰中。X射线衍射分析证实形成了几种水合化合物,这些化合物在火焰合成过程中分解,从而产生了多孔玻璃微球(PGM)。使用高浓度的活化碱溶液有利于形成孔隙。PGM的最高均匀性和产率对应于用9M氢氧化钾水溶液进行的活化。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fdc4/8838283/319b408515ed/materials-15-01043-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fdc4/8838283/f68974813cfb/materials-15-01043-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fdc4/8838283/7aa2e3bb3758/materials-15-01043-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fdc4/8838283/93a2670c9236/materials-15-01043-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fdc4/8838283/225ec7cc3cf5/materials-15-01043-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fdc4/8838283/319b408515ed/materials-15-01043-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fdc4/8838283/f68974813cfb/materials-15-01043-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fdc4/8838283/7aa2e3bb3758/materials-15-01043-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fdc4/8838283/93a2670c9236/materials-15-01043-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fdc4/8838283/225ec7cc3cf5/materials-15-01043-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/fdc4/8838283/319b408515ed/materials-15-01043-g005.jpg

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本文引用的文献

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Glassy Microspheres for Energy Applications.用于能源应用的玻璃微球。
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Waste glass from end-of-life fluorescent lamps as raw material in geopolymers.废荧光灯玻璃作为地聚合物的原料。
Waste Manag. 2016 Jun;52:245-55. doi: 10.1016/j.wasman.2016.04.003. Epub 2016 Apr 8.
通过碱活化和直接墨水书写将废弃玻璃升级转化为高性能光催化支架。
Heliyon. 2024 Jan 17;10(2):e24737. doi: 10.1016/j.heliyon.2024.e24737. eCollection 2024 Jan 30.
4
Recent Progress in Modifications, Properties, and Practical Applications of Glass Fiber.玻璃纤维的改性、性能及实际应用的最新进展。
Molecules. 2023 Mar 8;28(6):2466. doi: 10.3390/molecules28062466.
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Advanced Dye Sorbents from Combined Stereolithography 3D Printing and Alkali Activation of Pharmaceutical Glass Waste.基于立体光刻3D打印与药用玻璃废料碱活化相结合的先进染料吸附剂
Materials (Basel). 2022 Oct 1;15(19):6823. doi: 10.3390/ma15196823.